The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
=Hatchett Brown= is copper potassium ferrocyanide. It is obtained by
precipitating a soluble copper salt with potassium ferrocyanide. Copper
salts behave towards potassium ferrocyanide in the same manner as iron
salts; different compounds result according as the ferrocyanide or the
copper salt is in excess. Hatchett brown is somewhat largely used for
painting wood.
=Chrome Brown.=—When solutions of potassium chromate and a copper
salt are mixed a precipitate of the composition CuCrO₄.2CuO.2H₂O is
obtained. On drying it acquires a fine brown colour; it forms a very
stable pigment.
Chrome brown can also be made by dissolving 10 parts of potassium
bichromate in 20 parts of water, heating to boiling, adding 13·5 parts
of solid copper chloride and then gradually a boiling solution of 10
parts of soda in 20 parts of water, until effervescence no longer takes
place. On cooling, chrome brown separates as a soft brown precipitate.
=Cobalt Brown= is a very durable compound pigment of a pleasing shade.
It is obtained in various hues by adding ferric oxide to the mixture
of alumina and a cobalt salt used for making cobalt blue. The process
may also be carried out by igniting ammonia alum with cobalt sulphate
and ferrous sulphate. The temperature required in this case to obtain a
bright colour is very high, and must be maintained for a long time to
decompose the whole of the ferrous sulphate.
The pigment can be obtained at a far lower temperature when ferric
chloride is used in place of ferrous sulphate. The mixture is made by
grinding together 5 parts of cobalt hydroxide and 25 parts of ammonia
alum, then adding a solution of ferric chloride, rapidly drying the
whole to a powder, and whilst still hot filling it into the crucible
in which the ignition is performed. When small quantities of ferric
chloride are used chocolate brown shades inclining to violet are
produced; the larger the quantity of the iron compound the more pure is
the brown.
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