The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
The combustion in the flue must be conducted with care, it should
proceed at the lowest possible temperature, but this should not sink
below a certain minimum. If the fire is too strong the greater portion
of the carbon is burnt, which would otherwise be obtained as soot; the
yield of soot is very small, and generally only ”dust soot” would be
obtained, without any quantity of ”flying soot”. On the other hand, if
too little air enters, so that the combustion takes place at too low
a temperature, a large yield of soot is obtained, but it is of poor
quality. Soot obtained by combustion at too low temperatures has not a
pure black but a perceptibly brown colour; it has not the flocculent
nature of the best product, a small weight of which occupies a very
large volume, but is greasy and has a high specific gravity. The
lower the temperature used in producing soot black, the further is
the chemical change removed from that of ordinary combustion, and the
nearer to that of dry distillation. Soot produced with an insufficient
supply of air contains a considerable quantity of liquid and solid
products of dry distillation, which give it a brown colour and the
above-mentioned greasy nature.
In many soot works the air supply is regulated in a most primitive
manner: the workman places against the openings by which air is
admitted to the burning materials a larger or smaller number of bricks
according as the combustion appears to be too rapid or too slow.
Unfortunately there is no clear sign to indicate the temperature most
favourable for the production of the greatest quantity of soot, the
appearance of the flame alone can be taken as a guide. If the flame
appears pure white and very luminous and shows at its end no thick
black smoke the combustion is very complete, and but a very small yield
of soot is to be expected. On the other hand, if the flame continually
threatens to go out the air supply is too small and a liberal amount of
soot will be formed, but mixed with a large quantity of the products
of dry distillation. As far as it can be described in words the flame
should appear as follows: The colour should be a murky red, similar to
that of the flame of a bad tallow candle; in shape the flame should be
a long drawn out tongue, from the point of which a thick black smoke is
clearly seen. The soot deposits in the long board flues in the form of
flocks or dust. The properties of the soot which is deposited in the
different parts of the long flue vary according to the distance from
the place of combustion, near to which a good black soot is deposited,
requiring, however, long grinding with oil or gum solution to form a
good paint. At a greater distance the soft and very fine ”flying soot”
is deposited; it is the most pure black and is regarded as the best
quality. The soot deposited farther on is more and more brown, and
has a more greasy nature the greater the distance from the place of
combustion.
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