The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
The operation of grinding the gold is very lengthy; it considerably
increases the cost of the already expensive material. The process may
be considerably shortened if the gold is obtained in a very finely
divided state by a chemical operation. For this process coins or broken
jewellery is heated in hydrochloric acid, and nitric acid gradually
added. The gold dissolves in the mixture. If it was alloyed with silver
a white precipitate of silver chloride is formed, which is filtered off
after largely diluting with distilled water. The solution is boiled
for some time to remove excess of nitric acid. A solution of ferrous
sulphate is then added; the liquid at once becomes bluish black, and
in a short time deposits a brown precipitate composed of chemically
pure gold, which is so finely divided that it is almost without the
characteristic glitter of gold. The precipitate is filtered off, dried
and preserved in stoppered bottles. In order to prepare shell-gold
from this gold powder it is simply necessary to grind it with thick
gum solution in a porcelain mortar; under the pressure of the pestle
the gold rapidly acquires its natural glitter. The grinding need only
be continued until the gold and gum solution are uniformly mixed.
The mixture so made should be at once filled into the shells, since
on standing the gold would soon separate from the gum solution in
consequence of its high specific gravity.
=Shell-Silver.=—Genuine shell-silver can be made by rubbing silver leaf
with gum solution upon a slab exactly as genuine shell-gold. In this
case also the labour may be considerably lessened by converting the
silver into a state of fine division by a chemical process. Silver is
dissolved in nitric acid, which must be quite free from hydrochloric
acid, or insoluble silver chloride would be formed. In the operation
brown suffocating fumes are evolved which attack the respiratory
organs; it should therefore be conducted in the open air or under a
flue with a good draught. The silver solution, which is generally
coloured blue by admixed copper, is diluted with a large quantity of
distilled water. A sheet of copper is then dipped into the liquid and
rapidly moved about in it. The silver then separates as a dark grey
powder; after washing it is chemically pure, and when ground with gum
solution it produces genuine shell-silver.
Shell-silver and shell-gold are rarely used in painting on account of
their cost; they are chiefly used for illuminated manuscripts. When
these metallic pigments are to be used in oil painting, in place of
gum they must be ground with a liquid which mixes with boiled oil or
essential oils. For this purpose copaiba balsam is to be recommended.
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