The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
The vegetable bronze is obtained from logwood in a similar manner, a
solution of stannic chloride being generally used to precipitate the
lake when a deep bronze is required, and alum for a pale gold shade.
By using mixtures of the two salts intermediate shades are produced.
The precipitate produced by alum may be shaded by means of potassium
bichromate. Hæmatoxylin forms with chromium oxide a deep bluish black
compound which has such intense colouring power that it is used to
colour writing ink. The ink is prepared by adding a little potassium
bichromate to a decoction of logwood. If a very small quantity of this
dark precipitate is mixed with the lake precipitated from logwood
extract by alum solution, colours are produced possessing the peculiar
metallic lustre and a shade depending upon the quantity of potassium
bichromate added. The addition of this salt must be very carefully
made, as a very small excess is sufficient to render the colour so dark
that it is useless as a bronze. The shade of the precipitate depends
upon the concentration of the liquid and other conditions, so that
it is impossible to give precise quantities. In practice, the safest
and most convenient method is to dissolve the bichromate in a large
quantity of water and add very small quantities of the dilute solution
to the logwood extract along with the alum. After each addition a
portion of the precipitate is rapidly mixed with the above-mentioned
solution of soap and wax, to which a little size has been added, and
then spread upon paper. If the desired shade has not yet appeared, a
little more bichromate is added and another test made, and the process
repeated until the proper shade is attained.
Pigments for colouring wall papers and fancy leather are not easily
made which produce such fine effects at so small a cost as the
vegetable bronze pigments, which deserve the greatest regard from the
colour maker and leather and paper manufacturers.
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