The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
Brasilin is a weak acid of the composition C₁₆H₁₄O₅. It forms
handsomely coloured compounds with most metallic oxides, which are
much used in dyeing. A decoction of red wood gives with alum and
soda solution a handsome lake of a pure red colour. With a solution
of stannic chloride it at once produces a red precipitate. When a
solution of potassium chromate is added to a decoction of redwood, a
dark brown precipitate separates, which is a compound of chromium oxide
with the partially altered colouring matter. The decoction produces a
brownish red compound with ferric oxide.
The decoctions of red wood contain, in addition to the colouring
matter, a number of other substances which would injure the shade of
the lake obtained from the decoction. The greater portion of these
substances may be separated by allowing the decoction to stand for
several days, when a dirty reddish brown mud forms at the bottom of
the vessel. This simple method of purification is attended with the
disadvantage that, especially in summer, the decoction rapidly becomes
mouldy. This may be prevented by the addition of a little carbolic
acid; not more than 0·01 per cent. of the quantity of liquid is
required. The foreign matters may also be separated by adding milk or a
solution of glue to the decoction, but the simpler process of allowing
it to stand gives the best result.
From the behaviour of brasilin towards the metallic oxides, as given
above, it follows that compounds of different colours can be made from
red wood. These are utilised in dyeing, but in colour works red wood
is only used for the preparation of red lakes. The lakes are found in
commerce under numerous names, the most common of which are Venetian
lake, Vienna lake, Florentine lake, Berlin lake, etc. According as
the colouring matter is combined with alumina alone or with stannic
chloride in addition, pale or deep lakes are obtained. The different
shades of red wood lakes found in commerce are obtained by additions of
a white pigment. For this purpose levigated chalk, gypsum, lycopodium
powder, and other white pigments light in weight are used.
In preparing red wood lakes the decoction should always be purified by
the process mentioned above; there is then more certainty of obtaining
a bright lake. It is advisable to dilute the decoction considerably
with pure water before precipitating the lake; experience has shown
that brighter colours are thus obtained. To 100 parts of wood 130 to
150 parts of alum are used. The latter is dissolved alone and mixed
with the decoction, the lake is then precipitated by soda solution. As
the lake separates the liquid becomes lighter; portions should be taken
out of the vessel in order to see when all the colouring matter is
thrown down. If too much soda solution is added the lake takes a violet
shade.
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