The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
Whilst the percentage of indigo blue contained in indigo can be
found with tolerable accuracy, though by a rather elaborate process
requiring special apparatus, there is no convenient method for
examining the other organic colour materials by which their content
in active constituents can be readily found. In practice a process is
particularly valuable which requires little time and no complicated
apparatus. Colouring materials can be rapidly tested by a physical
process which requires little time and an inexpensive apparatus. Under
similar conditions the extract of a dye-wood is deeper in colour in
proportion to the colouring matter it contains. If therefore the
intensity of the colour of the extract can be accurately measured,
there is no difficulty in drawing a certain conclusion as to the amount
of colouring matter in the raw material.
[Illustration: FIG. 43.]
=The Colorimeter= is the apparatus adapted for the purpose in question.
There are many forms of colorimeter. The instrument devised by Dubosq
is distinguished by simplicity and accuracy of results before other
apparatus of similar construction. Dubosq’s colorimeter consists of the
following parts (Fig. 43): two glass cylinders, C and C₁, the bottoms
of which must be perfectly plane both inside and outside (the accuracy
of the results depends upon this), stand upon a sheet of plate glass.
Two glass cylinders of smaller diameter, T and T₁, are suspended in C
and C₁. The bottoms of these cylinders must also be quite plane. It
would be very expensive to make glass cylinders of this kind in one
piece. The same result is obtained by providing each cylinder with
a metal ring upon which screws another ring in which is cemented a
circular piece of plate glass.
Light should only reach the eye of the observer in a direction parallel
with the axis of the cylinders. C and C₁ are therefore blackened on
the outside. The inner cylinders, T and T₁, are fastened to racks
moving vertically. The distance through which the cylinder is moved
is measured by a scale on one of the racks. Above the cylinders T and
T₁ are Fresnel’s prisms. Below C and C₁ is a mirror, S, which can be
adjusted to throw light vertically upwards. Beams of light pass through
the plate glass and the bottoms of the cylinders C and T, C₁ and T₁,
unrefracted, they are then deviated by the Fresnel’s prisms so that the
observer looking down through the telescope, F, has a circular field of
view, one half of which is illuminated by the light passing through the
cylinder C, and the other by the beam passing through C₁. The intensity
of the light which has passed through the two cylinders can thus be
accurately compared.
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