The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
+------------+--------------------------+-----------------------+
|Temperature.|Crystallised Ammonia Alum.|Anhydrous Ammonia Alum.|
+------------+--------------------------+-----------------------+
| 0° C. | 5·22 | 2·62 |
| 10° ” | 9·16 | 4·50 |
| 20° ” | 13·66 | 6·57 |
| 30° ” | 19·29 | 9·05 |
| 40° ” | 27·27 | 12·35 |
| 50° ” | 36·51 | 15·90 |
| 60° ” | 51·29 | 21·95 |
| 70° ” | 71·97 | 26·09 |
| 80° ” | 103·08 | 35·19 |
| 90° ” | 187·82 | 50·30 |
| 100° ” | 421·90 | 70·83 |
+------------+--------------------------+-----------------------+
Of the different alums, ammonia alum contains the largest and potash
alum the smallest proportion of alumina. The composition of the three
commonly occurring alums is given in the following table:—
+--------------------+------------+----------+-------------+
| |Potash Alum.|Soda Alum.|Ammonia Alum.|
+--------------------+------------+----------+-------------+
|Potash, K₂O | 9·95 | | |
|Soda, Na₂O | | 6·80 | |
|Ammonia, NH₃ | | | 3·89 |
|Alumina, Al₂O₃ | 10·83 | 11·20 | 11·90 |
|Sulphuric acid, SO₃ | 33·71 | 34·90 | 36·10 |
|Water, H₂O₄ | 45·51 | 47·10 | 48·11 |
+--------------------+------------+----------+-------------+
Thus ammonia alum is to be preferred to soda alum and soda to potash
alum, whilst the latter is used on account of its greater purity. In
a colour works, in which large quantities of alum are used, it is
advantageous to work with ammonia alum which is recrystallised on the
works.
The alums and aluminium sulphate are the alumina compounds in ordinary
use in colour works; aluminium acetate could also be used if it were to
be had at a reasonable price.
=Alumina=, Al₂O₃ = 102, =and Hydrate of Alumina=.—Pure alumina, or
rather hydrate of alumina, is required in the preparation of many
colours. When the solution of an aluminium salt is precipitated by
soda, the carbonic acid escapes with effervescence, and a gelatinous
precipitate is formed which it is extremely difficult to wash clean.
The precipitate, which consists of hydrate of alumina, shrinks very
greatly in drying, and turns to a horny mass; when strongly heated it
loses water, and becomes a white, insoluble powder of anhydrous alumina.
Public-domain text, read in full here on John Shaqi.
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