The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
The method pursued by Ozouf, in France, is a considerable improvement
on Thénard’s process. Pure carbonic acid is used for the precipitation,
and white lead of similar composition to that produced by the Dutch
process is obtained, since the introduction of the carbonic acid can be
regulated according to the volume and strength of the lead solution,
and thus white lead of any desired composition can be produced. The
most elaborate precautions for the health of the work-people are taken.
The preparation of pure carbonic acid gas is based upon the absorption
of this gas from a mixture of gases by a solution of sodium carbonate,
and its evolution on heating the solution. The apparatus is shown in
Figs. 18 and 19. The products of combustion obtained from the stove,
_A_, are drawn by the air pump, _E_, through the pipe, _C_, into the
cooler, _B_, which is regularly fed with cold water by _D_. The gases
compressed in the receiver, _E´_, deposit moisture there, and then
proceed through 3 horizontal cylinders, _F_, of sheet-iron, provided
with agitators, in which the carbonic acid is absorbed by a cold
solution of sodium carbonate of 9° B. The unabsorbed gases escape
into the atmosphere through _G_ (Fig. 19). The sodium bicarbonate
solution is received in the wooden tank, _H_, after passing through
the 3 cylinders, _F_. The pump, _I_, of the alternating pump, _I I´_,
lifts the sodium bicarbonate solution out of _H_ and sends it through
the pipe, _K_, into the tubular cylinder, _J_, which stands upon a
cylinder of larger diameter, _J´_, communicating with it only by the
vertical tubes. The bicarbonate solution rises between the tubes in
_J_, passes through the pipe, _L_, drops in a fine spray through the
rose forming its mouth, and by means of the vertical tubes passes into
_J´_ and thence into _M_, where it is heated by means of a steam coil
to 100° C. Carbonic acid is then evolved, and the residual solution of
neutral sodium carbonate, after cooling in the vessel, _R_, by means
of the cold coil, is drawn off by the pump, _I´_, again to enter the
cylinders, _F_, by means of the pipe, _K_. The carbonic acid evolved
in _M_, together with steam, enters _J´_ through _N_, and in rising
in the tubes of the cylinder, _J_, is cooled by the falling spray
of bicarbonate solution. The cooling is completed in the coil, _O_,
surrounded by water; the vessel, _P_, separates the condensed water
and passes the gas on into the holder, _Q_. The pipe, _S_, connecting
_P_ with the suction pipe of the pump, _J´_, serves to restore to the
solution of sodium carbonate the water it has lost, thus maintaining
the proper concentration. The cost of 1 cubic metre of carbonic acid is
10 centimes, of 1 kilogramme 5 centimes.
[Illustration: FIG. 19.]
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