The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
In making lemon chrome, the tub in which the precipitation is to take
place is two-thirds filled with water, the lead solution is stirred
in, and then the chromate solution, mixed with the proper quantity
of sulphuric acid, is run in; the liquid is well stirred so that
the precipitate may form as quickly as possible throughout the whole
liquid. The precipitate is allowed to settle, the liquid drawn off, and
the colour washed twice with water as quickly as possible. The paste
is then removed from the tub and poured on a strong linen strainer.
At first, the fine precipitate goes through the strainer, the liquid
is poured back on the strainer until the size of its pores is so far
diminished by the precipitate itself that only clear liquid runs
through. The precipitate is left on the strainer until it forms a stiff
mass, which can be easily spread out upon boards by spatulas.
To obtain a good, that is, a loose product, it is necessary to carry
out the processes so quickly that the swelling mentioned above does not
take place while the colour is being strained, but when it has been
spread out on the boards. This swelling only takes place completely
when the layer of precipitate is fairly thin. Large boards should be
used, upon which the precipitate is spread out in a very thin layer.
To prevent the mass—which is still fairly fluid—from running off the
boards, they are provided with raised edges, and the paste is spread
out smoothly in these flat trays. If the operations have been properly
performed, the precipitate at once begins to swell and becomes of
a loose nature. When it has acquired a buttery consistency it is
cut up, by means of a thin sheet of brass, into prisms, which are
placed near one another standing on the narrow side, and dried first
in the shade and then in the sun. It is necessary that the drying
should take place slowly at first, or the cakes will crack or even
fall to pieces. The precipitate cannot be washed completely in the
tub, because it often begins to swell on the strainers, consequently
a crystalline crust covers the surface of the cakes during drying.
This layer must be removed by scraping the cakes of colour, in which
operation small quantities of chrome yellow dust become suspended
in the air. To protect the workman against poisoning by this lead
compound, precautions must be taken against breathing in the dust. The
simplest and most efficacious is to tie a wet sponge over mouth and
nose; this retains the particles of dust in the inspired air. The dust,
scraped off the cakes, is put into water, in which the salts dissolve,
whilst the chrome yellow sinks to the bottom. In this process for
preparing chrome yellow the solution of potassium acetate left after
the precipitation contains a considerable quantity of free acetic acid,
which may be utilised to dissolve lead.
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