The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
Red lead is made in two ways—directly from metallic lead or by heating
easily decomposed lead salts. When it is made from the metal, the
following is the process: the lead, which must be very pure, is melted
in a reverberatory or calcining furnace, oxidised to massicot by the
air passing over it, and the massicot then, by careful heating, changed
into red lead, a process in which particular care must be taken that
the mass is not melted. By continued heating the massicot absorbs about
2 per cent. of oxygen, and changes in colour to a bright red.
The art in making red lead by this process lies in maintaining
the proper temperature; the furnaces are constructed so that the
temperature may be regulated during the heating. A reverberatory
furnace is used, in which is a stirring apparatus, so that the heated
mass may be continually turned over to accelerate the oxidation. Muffle
furnaces are also used, in which the massicot is placed in crucibles on
an iron plate, which can be pulled out of the furnace for observation
of the change of colour. Whatever method is used, the temperature must
be so regulated that over-heating of the material is avoided, otherwise
litharge is formed, which is only very slowly converted into red lead.
[Illustration: FIG. 26.]
Mercier states that the muffle furnaces are arranged as shown in Fig.
25. The muffle, _a_, is 2·5 metres long and 2 metres wide; its bottom
rests on an iron plate. The passage, _d_, running under the muffle
is 20 centimetres high; it is divided by a partition, and at each
end are two hearths, _c_, 70 centimetres long and wide. The products
of combustion pass from the long passages into side channels, _f_,
provided with dampers, go round the muffle and unite in the space, _g_.
The flue, _k_, at the back of the muffle is provided with dampers, _m_,
which exactly regulate the current of air through the muffle; _n_ is
the chamber in which are collected the particles of oxide carried over
by the draught. The furnaces used for manual labour consist, according
to Percy (Figs. 26 and 27) of a rectangular or circular hearth, _a_,
of about 3 metres diameter, which is deeper in the middle and has two
fireplaces, _b_. The low arch surmounting the hearth is covered with
sand in order to prevent cooling.
[Illustration: FIG. 27.]
When finished, the red lead is drawn out of the furnace and finely
ground under edge-runners, or occasionally levigated. The temperature
necessary in making red lead is that at which the angles of the
muffles, when these are used, begin to show a dark red glow.
Public-domain text, read in full here on John Shaqi.
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