The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-MakingSindall, R. W. (Robert Walter)
History
The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-Making
Sindall, R. W. (Robert Walter)
Papermaking
The liability of papers to decay, in respect of the fibrous
composition, is almost in direct proportion to the severity of
the chemical treatment necessary to convert the raw material into
cellulose, and the extent of the deviation of the fibre from pure
cellulose is a measure of the degradation which is to be expected. The
behaviour of the fibres towards caustic soda or any similar hydrolytic
agent serves to distinguish the fibres of maximum durability from
those of lesser resistance. It may be noted that in the former the
raw materials, viz., cotton, linen, hemp, ramie, etc., contain a high
percentage of pure cellulose, while in the latter the percentage of
cellulose is very much lower, such fibres as esparto, straw, wood,
bamboo, etc., giving only 40-50 per cent. of cellulose. The two
extremes are represented by pure cotton rag and mechanical wood pulp.
Other things being equal, the decay which may take place in papers
containing the fibre only, without the admixture of size or chemicals,
may be considered as one of oxidation, which takes place slowly in
cotton, and much more rapidly with mechanical wood pulp. Experimental
evidence of this oxidation is afforded when thin sheets of paper made
from these materials are exposed to a temperature of 100° to 110° C.
in an air oven. The cotton paper is but little affected, while the
mechanical wood pulp paper soon falls to pieces.
The order of durability of various papers in relation to the fibrous
constituents may be expressed thus: (1) rag cellulose; (2) chemical
wood cellulose; (3) esparto, straw, and bamboo celluloses; (4)
mechanical wood pulp. The rate and extent of oxidation is approximately
shown by the effect of heat as described. The differences between
the celluloses are also shown by heating strips of various papers in
a weak solution of aniline sulphate, which has no effect on wood or
rag cellulose, dyes esparto and straw a pinkish colour, and imparts a
strong yellow colour to mechanical wood pulp and jute.
_Physical Qualities._--The permanence of a paper depends not only upon
the purity of the fibrous constituents and the freedom from chemicals
likely to bring about deterioration, but also upon the general physical
properties of the paper itself. Other things being equal, the more
resistant a paper is to rough usage the longer will it last. The reason
why rag papers are so permanent is that not only is the chemical
condition of the cellulose of the highest order, but the physical
structure of the fibre is such that the strength of the finished paper
is also a maximum.
The methods of manufacture may be modified to almost any extent, giving
on the one hand a paper of extraordinary toughness, or on the other
hand a paper which falls to pieces after a very short time. Thus a
strong bank-note paper may be crumpled up between the fingers three
or four hundred times without tearing, while an imitation art paper is
broken up when crumpled three or four times.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account