The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-MakingSindall, R. W. (Robert Walter)
History
The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-Making
Sindall, R. W. (Robert Walter)
Papermaking
The demand for an abnormally white paper is indirectly the cause of
deterioration in colour, but in this case the ultimate effect is not a
fading but a discoloration of white to a more or less distinct yellow
or brown colour, due to changes in the fibre which may often be traced
to excessive bleaching. In this case the fading of colour is directly
due to deterioration of the paper itself, and may occur in celluloses
of the best type. With lower-grade papers containing mechanical wood
pulp the degradation of colour and fibre is inevitable.
_Air and Moisture._--The exact effects produced on paper freely
exposed, or in books as ordinarily stored, depend upon the condition of
the atmosphere. Pure air has little or no action upon paper, cellulose
being a remarkably inert substance, and even in impure mechanical wood
pulp, if merely exposed to pure dry air, the signs of decay would be
delayed considerably. The combined action of air and moisture is of a
more vigorous character in promoting oxidation changes in the fibres,
or a dissociation of the sizing and other chemical ingredients of the
paper. The presence of moisture is, indeed, absolutely essential for
the reaction of some substances upon one another, and it is easy to
show that certain chemical compounds can be left in ultimate contact,
if absolutely dry, for a lengthened period without reacting, but the
addition of a little moisture at once produces chemical union. This may
be shown by a simple experiment.
Thus a piece of coloured paper which may be bleached immediately
if suspended in an atmosphere of ordinary chlorine gas will remain
unbleached for several hours if first thoroughly dried in an oven and
exposed to dry gas.
In the case of books and papers, these conditions which promote slow
disintegration are aggravated by the presence of impurities in the
air, such as the vapours of burning gas, the traces of acidity in
the atmosphere of large manufacturing towns, the excessive dampness
and perhaps heat of a climate favouring the growth of organisms. All
these factors are of varying degrees in different places, so that the
deterioration of papers does not proceed in the same measure and at the
same rate everywhere.
_Moisture._--It may not be out of place to discuss some important
relations between moisture and the physical qualities of a sheet of
paper. A paper in its normal condition always contains a certain
proportion of water as one of its ingredients, and the presence of this
moisture has much to do with the strength, elasticity, and use of the
paper, the absence of moisture giving rise to defects and troubles in
the use of the paper which to a certain extent lower its commercial
value and deteriorate it, though not perhaps in the sense of permanent
degradation of quality.
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