The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-MakingSindall, R. W. (Robert Walter)
History
The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-Making
Sindall, R. W. (Robert Walter)
Papermaking
The best parchment is made from pure cellulose such as rag or chemical
wood pulp. The quality of the parchment depends upon attention to the
strength of the acid, the temperature of the acid bath, the period of
immersion, the complete removal of the acid, and the careful drying of
the wet parchment.
[Illustration: FIG. 43.--Apparatus for making Parchment Paper.]
The acid is employed at a strength of 1·71 specific gravity, being
prepared by diluting the commercial concentrated acid in a leaden
vessel, with a sufficient quantity of water.
The parchment is generally prepared by passing a continuous sheet of
paper through a bath of acid of the proper strength at a speed which
ensures the correct period of immersion. As the treated paper leaves
the bath it passes through squeezing rolls which remove the excess of
acid, and the paper is then led through a series of tanks containing
fresh water, the last traces of acid being neutralised by small
additions of ammonia, or some alkali, to the last washing tank. The wet
parchment is then passed through suitable rollers and carefully dried
over cylinders heated internally by steam. The paper is kept perfectly
stretched as it dries, because it shrinks enormously, and would
otherwise become cockled and uneven.
Thick sheets of parchment paper are frequently made by passing three
sheets of paper through the acid bath and bringing them together
between the rollers before washing. The sheets unite when pressed
together; the remainder of the process being the same as that employed
for single sheets.
The parchment exhibits remarkable differences to the original paper,
the strength being increased three or four times, the density about 30
per cent., the latter being shown by the shrinkage, which amounts to at
least 30 per cent.
_Vulcanised Paper._--Zinc chloride has the property of parchmentising
paper in a manner similar to sulphuric acid. The product obtained when
this reagent is used is generally termed vulcanised fibre. The paper
is passed as a continuous sheet into a bath of strong zinc chloride,
having a density of 160-170 Twaddell, which causes the cellulose to
swell up and partly gelatinise. A very large excess of strong zinc
chloride is necessary, and the process is only rendered commercially
possible by careful recovery of the zinc from the washing waters, which
are submitted to chemical treatment.
The _vulcanised_ product is subsequently treated with nitric acid or
with a mixture of nitric and sulphuric acids to render them waterproof.
Dextrin is frequently employed to retard the chemical action to permit
of the necessary manipulation of the material before it is finally
washed. The complete removal of the excess of zinc and acid is a
necessary feature of the whole operation.
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