The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-MakingSindall, R. W. (Robert Walter)
History
The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-Making
Sindall, R. W. (Robert Walter)
Papermaking
Advantage is taken of this fact to carry out a process of incineration
on a large scale, so that heat derived from the burning off of the
resinous mass is utilised for evaporation of weaker liquors. The ash is
drawn from special furnaces, put aside, and allowed to char quietly, so
that the carbonaceous matter is more or less completely burnt away. The
ash in this form contains about 40 per cent. of soda, its composition
being determined by the nature of the fibre which has been treated. In
the case of straw, the amount of silicate is considerable, as shown by
the following typical analysis:--
Sodium carbonate 70·2
Sodium hydrate 2·3
Sodium sulphate 4·1
Sodium chloride 7·5
Silica 7·5
Oxides of iron and alumina 0·75
Unburnt carbon, etc. 7·65
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100·00
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At the present time there is no process in general use for the recovery
of the liquors used in the treatment of wood by the sulphite process.
Many schemes have been proposed, the most promising of which is that of
Drewsen.
_Sulphur and Sulphites._--The pale yellow brittle substance known as
sulphur is too familiar to require any detailed description. It unites
with oxygen in various proportions, and these in contact with water
form the various sulphur acids known to commerce. Sulphur burned with a
limited quantity of air forms sulphurous acid gas, and this substance
is the chief product of oxidation, which by further treatment can be
converted into sulphites.
In the manufacture of the sulphur compounds required in the preparation
of wood pulp, the furnace for burning the sulphur consists of a
flat-bottomed cast iron retort which is very shallow, and provided with
a curved top, to which a pipe is fixed, so that the sulphurous acid may
be conveyed away from the furnace. In the most recent form of sulphur
oven a small conical-shaped revolving furnace is employed, which
produces a satisfactory gas of constant composition very economically.
_Bisulphite of Lime._--This compound is obtained when the sulphurous
acid gas is brought into contact with moistened limestone. In the
manufacture of bisulphite of lime on a large scale the sulphurous acid
gas is drawn or pumped up tall circular towers filled with blocks of
limestone, kept moistened by a carefully regulated stream of water
flowing from the top of the tower.
In another system known as the acid tank process, the gas is forced
into large circular vats containing milk of lime.
Public-domain text, read in full here on John Shaqi.
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