The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-MakingSindall, R. W. (Robert Walter)
History
The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-Making
Sindall, R. W. (Robert Walter)
Papermaking
_Bleaching Powder._--This substance is prepared on a large scale by
allowing chlorine gas to act upon dry slaked lime. The lime absorbs
nearly one-half its weight of chlorine and forms a dry white powder,
having a very pungent odour. The best bleaching powder contains about
37 per cent. of what is termed "available chlorine." The substance,
on being treated with water, gives a greenish-coloured solution known
as bleach liquor, and when raw paper-making material, after having
been digested with caustic soda, is treated with this solution, it is
gradually bleached to a white colour. The composition of the powder may
be represented approximately as follows:--
Available chlorine (combined with lime) 36·00
Chlorine in the form of chloride 0·32
Chlorine in the form of chlorate 0·26
Lime 44·66
Magnesia 0·43
Silica, iron oxides, etc. 1·33
Insoluble matter 17·00
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100·00
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Since the amount of bleach used for wood pulps varies from 8 per cent.
to 25 per cent. of powder on the dry wood pulp, the cost of bleaching
in some cases is considerable. The economy of the process depends in
some measure upon the care exercised in the purchase of bleaching
powder of standard quality, the storage of same in a dark, cool place,
and the efficient treatment or exhaustion of the powder when the bleach
liquor is prepared.
The powder is usually agitated for about an hour with water sufficient
to produce a liquor of 13°-15° Twaddell. The undissolved powder is
allowed to settle and the clear solution siphoned off, after which
the sediment is washed once or twice to remove all the soluble matter
completely.
BLEACH LIQUOR TABLE.
Showing for bleaching powder solutions of known density the quantity
of powder necessary to produce 100 gallons of liquor and the
number of gallons obtained from 1 cwt. of powder (adapted from
Lunge and Beichofen).
Public-domain text, read in full here on John Shaqi.
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