The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-MakingSindall, R. W. (Robert Walter)
History
The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-Making
Sindall, R. W. (Robert Walter)
Papermaking
_Starch._--This substance is used in many classes of paper for
improving the surface and finish. It is added to the pulp in the
beating engine in the dry form as powder, or in the form of starch
paste, produced by boiling the starch in water.
The viscosity of the starch paste is somewhat increased by the addition
of a small quantity of alkali, but due care must be exercised in
boiling, which should only be carried out sufficiently to cause the
starch granules to burst, as any excessive boiling causes the starch
paste to lose some of its viscosity.
The presence of starch in paper is detected by the blue coloration
produced when the paper is dipped into a weak solution of iodine. The
determination of the exact percentage of starch in a paper is a matter
of some difficulty.
_Silicate of Soda._--The precipitation of gelatinous silica upon the
pulp in the beating engine is generally regarded as favourable to the
production of a sheet of paper having what is known as a harder finish.
The precipitation is effected by adding a solution of silicate of soda
to the beating engine, with the subsequent addition of sufficient
sulphate of alumina to react with the silicate of soda.
ANALYSIS OF COMMERCIAL ALUMS.
(Griffin and Little.)
---------------------------------+------+------+------+------
| (1) | (2) | (3) | (4)
---------------------------------+------+------+------+------
Insoluble in water | 0·05| 10·61| 0·11| 0·56
Alumina (Al_{2}O_{3}) | 15·47| 14·96| 11·64| 16·58
Iron protoxide (FeO) | 0·02| 0·13| 0·06| --
Iron sesquioxide (Fe_{2}O_{3}) | 0·00| 1·08| 1·17| 0·04
Zinc oxide (ZnO) | -- | -- | -- | --
Soda (Na_{2}O) | 1·72| 0·57| 4·75| 0·56
Magnesia (MgO) | -- | -- | 0·45| --
Sulphuric acid (SO_{3}) combined | 37·26| 37·36| 35·98| 39·17
Sulphuric acid (SO_{3}) free | -- | 1·08| 5·13| --
Water by difference | 45·48| 34·21| 40·71| 43·09
---------------------------------+------+------+------+------
|100·00|100·00|100·00|100·00
------------------------------- -+------+------+------+------
Sizing test (parts of dry neutral| | | |
rosin size precipitated by one | | | |
part of the alum) | 3·32| 3·47| 3·19| 3·71
------------------------------- -+------+------+------+------
TABLE SHOWING VALUE OF SOLUTIONS OF ALUMINIUM SULPHATE.
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