The total energy is the product QI, _i.e._ the product of the total
quantity by the total intensity at our disposal. The transformed energy is
Q(I - I'), the product of the total quantity by the difference of intensity
at the inlet and at the outlet of the machine. The formula for efficiency
thus becomes
Q(I - I') / QI = (I - I') / I.
If I represents a temperature, then in order that the efficiency may be
positive I' must be less than I, {104} there must be a fall of temperature
in the machine. If I' were greater than I, _i.e._ if the temperature at the
outlet were greater than that at the inlet, the efficiency would be a
negative one, and the transformer would have to borrow heat from some
external source.
_Entropy._--In every transformation of energy a certain portion of the
energy is transformed into heat: a lamp gives out useless heat as well as
light, a machine gives out useless heat as well as mechanical work. This
loss of useful energy as heat occurs in every transference or
transformation of energy; it is only in the case of heat passing from a
hotter to a colder body that there is no such transformation. When equality
of temperature is established there has been no loss of energy, but the
whole of the energy has become unutilizable, i.e. untransformable. In the
formula of efficiency the fall of intensity I - I' is now zero, and
therefore the efficiency of the machine
(I - I') / I
is also zero.
Since in all its transformations a certain fraction of the energy is
changed into heat, there is a tendency in nature for all differences of
temperature to become equalized. Hence the quantity of utilizable energy in
the universe tends to diminish. Clausius called this unutilizable energy
enmeshed in the substance of a body its entropy, and showed that in every
transformation the amount of this unutilizable energy tended to increase.
"The entropy of a system always tends towards a maximum value."
Public-domain text, read in full here on John Shaqi.
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