The Natural History of ClaySearle, Alfred B. (Alfred Broadhead)
Science
The Natural History of Clay
Searle, Alfred B. (Alfred Broadhead)
Clay
(_e_) _Clay Substance._ A general term indicating any of the foregoing
or a mixture of them; it is also applied (unwisely) to the material
obtained when a natural clay is freed from its coarser impurities by
elutriation (p. 7).
The Chief Characteristics of 'True Clay' from Different Sources.
In so far as it can be isolated _true clay_ appears to be an amorphous,
or practically amorphous, material which may under suitable conditions
crystallize into rhombic plates of kaolinite. The particles of which it
is composed are extremely small, being always less than 0·0004 in. in
diameter. They adsorb dyes from solutions and show other properties
characteristic of colloid substances though in a very variable degree,
some clays appearing to contain a much larger proportion of colloidal
matter than do others. To some extent the power of adsorption of salts
and colouring matters appears to be connected with the plasticity (p.
41) of the material, but this latter property varies so greatly in
clayite or pelinite from different sources as to make any generalization
impossible.
True clay substance appears to be quite white, any colour present being
almost invariably traceable to ferric compounds or to carbonaceous
matter. The latter is of small importance to potters as it burns away in
the kiln. The specific gravity of clay substance is 2·65 according to
Hecht, the lower figures sometimes reported being too low. Its hardness
is usually less than that of talc--the softest substance on Mohs'
scale--but some shales are so indurated as to scratch quartz. It is
quite insoluble in water and in dilute solutions of acids or alkalies,
but is decomposed by hydrofluoric acid and by concentrated sulphuric
acid when heated, alumina entering into solution and silica being
precipitated in a colloidal condition.
It absorbs water easily until a definite state of saturation has been
reached, after which it becomes impervious unless the proportion of
water is so large and the time of exposure so great that the material
falls to an irregular mass which may be converted into a slurry of
uniform consistency by gently stirring it. With a moderate amount of
water, pelinite develops sufficient plasticity to enable it to be
modelled with facility, but clayite and some specimens of pelinite are
somewhat deficient in this respect. The pelinitic particles usually
possess the capacity to retain their plasticity after being mixed with
considerable proportions of sand or other non-plastic material and are
then said to possess a high binding power (p. 28).
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