The Natural History of ClaySearle, Alfred B. (Alfred Broadhead)
Science
The Natural History of Clay
Searle, Alfred B. (Alfred Broadhead)
Clay
On still further raising the temperature of pure clay (pelinite or
clayite) no further reactions of importance occur, the material being
practically infusible. If, however, any silica, lime, magnesia,
alkalies, iron oxide or other material capable of combining with the
alumina and silica is present as impurities in the clay substance,
combination begins at temperatures above 900° C. This causes a reduction
of the heat-resisting power of the material; the silicates and
alumino-silicates produced fuse and begin to react on the remaining
silica and alumina, first forming an impermeable mass in place of the
porous one produced with pure clay substance, and gradually, as the
material loses its shape, producing a molten slag if the 'clay' is
sufficiently impure. As ordinary clays are never quite free from
metallic compounds other than alumina, this formation of a fused
portion--technically known as _vitrification_ (p. 37)--occurs at
temperatures depending on the nature of the materials present, so that a
wide range of products is obtained, the series commencing with the
entirely unfused pure clay (china clay), passing through the slightly
vitrified fireclays, the more completely vitrified ball clays to the
vitrifiable stoneware clays and ending with materials so rich in easily
fusible matter as scarcely to be worthy of the name of clays.
The constitution of the clay molecule is a subject which has attracted
the attention of many investigators and is being closely studied at the
present time. It is a subject of peculiar difficulty owing to the
inertness of clay substance at all but high temperatures, and to the
complexity of reactions which take place as soon as any reagent is
brought into active connection with it.
Without entering into details regarding the various graphic formulae
which have been suggested, it is sufficient to state that the one which
is most probably correct, as far as present knowledge goes, is Mellor's
and Holdcroft's re-arrangement of Groth's formula (30)
HO\ /OSiO\
\Al2/ \O
/ \ /
HO/ /\ \OSiO/
/ \
HO OH
which on removal of the hydroxyl groups might be expected to give the
anhydride
O\\ /OSiO\
\\Al2/ \
// \ /
O// \OSiO/
though in practice this substance--if formed at all--appears to be
instantly split up into Al2O3 and SiO2.
Public-domain text, read in full here on John Shaqi.
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