The Natural History of ClaySearle, Alfred B. (Alfred Broadhead)
Science
The Natural History of Clay
Searle, Alfred B. (Alfred Broadhead)
Clay
The view that clays may be regarded as impure varieties of clayite is
considered erroneous by several investigators for various reasons. For
instance, felspar is rarely found in china clays, but is a common
constituent of secondary (plastic) clays. J. M. van Bemmelen (26), who
has found that the alumina-silica ratio of clays produced by weathering
is always higher than that in clays of the china clay type produced by
hypogenic action. In a number of clays examined he found that a portion
was soluble in boiling hydrochloric acid whereas clayite is scarcely
affected by this treatment. He also found a varying proportion of
alumino-silicate insoluble in hydrochloric acid but dissolved on
treatment with boiling sulphuric acid and subsequently with caustic soda
solution; this latter he considers to be true clayite. Unfortunately,
his results were obtained by treating the crude clay with acid, instead
of first removing such non-plastic materials as can be separated by
washing, so that all that they show is that some clays contain
alumino-silicates of a nature distinct from clayite in addition to any
clayite which may be found in them.
The fact that all clays when heated to 700 or 800° C. readily react with
lime-water to form the same calcium silicates and aluminates indicates
so close a resemblance between the clay substance obtainable from
different sources as to constitute strong evidence of the identity of
this substance with clayite or with materials so analogous to it as to
be indistinguishable from it under present conditions.
In all probability, the plastic clays have been derived from a somewhat
greater variety of minerals than the primary clays (p. 71) and under
conditions of decomposition which differ in details, though broadly of
the same nature as those producing china clays. The presence of
colloidal matter suggests a more vigorous action--or even a
precipitation from solution--instead of the slower reactions which
result in the formation of the kaolinite crystals.
The much smaller particles present in plastic clays also indicate a more
complete grinding during the transportation of the material or some form
of precipitation. If, as Hickling suggests, all clays are direct
products of the decomposition of _mica_, the fact that several varieties
of mica are known and that the conditions under which these decompose
must vary considerably, afford a good, if incomplete, explanation of
some of the widely diverse characteristics observed in different clays.
Public-domain text, read in full here on John Shaqi.
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