It is to a German physicist, Giese, that we owe the first notions on
the mechanism of the conductivity of gases, as we now conceive it. In
two memoirs published in 1882 and 1889, he plainly arrives at the
conception that conduction in gases is not due to their molecules, but
to certain fragments of them or to ions. Giese was a forerunner, but
his ideas could not triumph so long as there were no means of
observing conduction in simple circumstances. But this means has now
been supplied in the discovery of the X rays. Suppose we pass through
some gas at ordinary pressure, such as hydrogen, a pencil of X rays.
The gas, which till then has behaved as a perfect insulator,[29]
suddenly acquires a remarkable conductivity. If into this hydrogen two
metallic electrodes in communication with the two poles of a battery
are introduced, a current is set up in very special conditions which
remind us, when they are checked by experiments, of the mechanism
which allows the passage of electricity in electrolysis, and which is
so well represented to us when we picture to ourselves this passage as
due to the migration towards the electrodes, under the action of the
field, of the two sets of ions produced by the spontaneous division of
the molecule within the solution.
[Footnote 29: At least, so long as it is not introduced between the
two coatings of a condenser having a difference of potential
sufficient to overcome what M. Bouty calls its dielectric cohesion. We
leave on one side this phenomenon, regarding which M. Bouty has
arrived at extremely important results by a very remarkable series of
experiments; but this question rightly belongs to a special study of
electrical phenomena which is not yet written.]
Let us therefore recognise with J.J. Thomson and the many physicists
who, in his wake, have taken up and developed the idea of Giese, that,
under the influence of the X rays, for reasons which will have to be
determined later, certain gaseous molecules have become divided into
two portions, the one positively and the other negatively electrified,
which we will call, by analogy with the kindred phenomenon in
electrolysis, by the name of ions. If the gas be then placed in an
electric field, produced, for instance, by two metallic plates
connected with the two poles of a battery respectively, the positive
ions will travel towards the plate connected with the negative pole,
and the negative ions in the contrary direction. There is thus
produced a current due to the transport to the electrodes of the
charges which existed on the ions.
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