Other facts, moreover, will give to this hypothesis a still greater
value; we shall even be able, so to speak, to grasp these ions
individually, to count them, and to measure their charge.
§ 2. THE CONDENSATION OF WATER-VAPOUR BY IONS
If the pressure of a vapour--that of water, for instance--in the
atmosphere reaches the value of the maximum pressure corresponding to
the temperature of the experiment, the elementary theory teaches us
that the slightest decrease in temperature will induce a condensation;
that small drops will form, and the mist will turn into rain.
In reality, matters do not occur in so simple a manner. A more or
less considerable delay may take place, and the vapour will remain
supersaturated. We easily discover that this phenomenon is due
to the intervention of capillary action. On a drop of liquid a
surface-tension takes effect which gives rise to a pressure which
becomes greater the smaller the diameter of the drop.
Pressure facilitates evaporation, and on more closely examining this
reaction we arrive at the conclusion that vapour can never
spontaneously condense itself when liquid drops already formed are not
present, unless forces of another nature intervene to diminish the
effect of the capillary forces. In the most frequent cases, these
forces come from the dust which is always in suspension in the air, or
which exists in any recipient. Grains of dust act by reason of their
hygrometrical power, and form germs round which drops presently form.
It is possible to make use, as did M. Coulier as early as 1875, of
this phenomenon to carry off the germs of condensation, by producing
by expansion in a bottle containing a little water a preliminary mist
which purifies the air. In subsequent experiments it will be found
almost impossible to produce further condensation of vapour.
But these forces may also be of electrical origin. Von Helmholtz long
since showed that electricity exercises an influence on the
condensation of the vapour of water, and Mr C.T.R. Wilson, with this
view, has made truly quantitative experiments. It was rapidly
discovered after the apparition of the X rays that gases that have
become conductors, that is, ionised gases, also facilitate the
condensation of supersaturated water vapour.
Public-domain text, read in full here on John Shaqi.
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