Professor Pringsheim has succeeded, in certain cases, in finding the
dividing line between the phenomena of luminescence and that of
incandescence. Thus the former takes a predominating importance when
the gas is rendered luminous by electrical discharges, and chemical
transformations, especially, play a preponderant rôle in the emission
of the spectrum of flames which contain a saline vapour. In all the
ordinary experiments of spectrum analysis the laws of Kirchhoff cannot
therefore be considered as established, and yet the relation between
emission and absorption is generally tolerably well verified. No doubt
we are here in presence of a kind of resonance phenomenon, the gaseous
atoms entering into vibration when solicited by the ether by a motion
identical with the one they are capable of communicating to it.
If we are not yet very far advanced in the study of the mechanism of
the production of the spectrum,[47] we are, on the other hand, well
acquainted with its constitution. The extreme confusion which the
spectra of the lines of the gases seemed to present is now, in great
part at least, cleared up. Balmer gave some time since, in the case of
the hydrogen spectrum, an empirical formula which enabled the rays
discovered later by an eminent astronomer, M. Deslandres, to be
represented; but since then, both in the cases of line and band
spectra, the labours of Professor Rydberg, of M. Deslandres, of
Professors Kayzer and Runge, and of M. Thiele, have enabled us to
comprehend, in their smallest details, the laws of the distribution of
lines and bands.
[Footnote 47: Many theories as to the cause of the lines and bands of
the spectrum have been put forward since this was written, among which
that of Professor Stark (for which see _Physikalische Zeitschrift_ for
1906, passim) is perhaps the most advanced. That of M. Jean Becquerel,
which would attribute it to the vibration within the atom of both
negative and positive electrons, also deserves notice. A popular
account of this is given in the _Athenæum_ of 20th April 1907.--ED.]
These laws are simple, but somewhat singular. The radiations emitted
by a gas cannot be compared to the notes to which a sonorous body
gives birth, nor even to the most complicated vibrations of any
elastic body. The number of vibrations of the different rays are not
the successive multiples of one and the same number, and it is not a
question of a fundamental radiation and its harmonics, while--and this
is an essential difference--the number of vibrations of the radiation
tend towards a limit when the period diminishes infinitely instead of
constantly increasing, as would be the case with the vibrations of
sound.
Thus the assimilation of the luminous to the elastic vibration is not
correct. Once again we find that the ether does not behave like matter
which obeys the ordinary laws of mechanics, and every theory must take
full account of these curious peculiarities which experiment reveals.
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