The idea of the discontinuity of matter forces itself upon us for many
other reasons. All modern chemistry is founded on this principle; and
laws like the law of multiple proportions, introduce an evident
discontinuity to which we find analogies in the law of electrolysis.
The elements of bodies we are thus brought to regard might, as regards
solids at all events, be considered as immobile; but this immobility
could not explain the phenomena of heat, and, as it is entirely
inadmissible for gases, it seems very improbable it can absolutely
occur in any state. We are thus led to suppose that these elements are
animated by very complicated movements, each one proceeding in closed
trajectories in which the least variations of temperature or pressure
cause modifications.
The atomistic hypothesis shows itself remarkably fecund in the study
of phenomena produced in gases, and here the mutual independence of
the particles renders the question relatively more simple and,
perhaps, allows the principles of mechanics to be more certainly
extended to the movements of molecules.
The kinetic theory of gases can point to unquestioned successes; and
the idea of Daniel Bernouilli, who, as early as 1738, considered a
gaseous mass to be formed of a considerable number of molecules
animated by rapid movements of translation, has been put into a form
precise enough for mathematical analysis, and we have thus found
ourselves in a position to construct a really solid foundation. It
will be at once conceived, on this hypothesis, that pressure is the
resultant of the shocks of the molecules against the walls of the
containing vessel, and we at once come to the demonstration that the
law of Mariotte is a natural consequence of this origin of pressure;
since, if the volume occupied by a certain number of molecules is
doubled, the number of shocks per second on each square centimetre of
the walls becomes half as much. But if we attempt to carry this
further, we find ourselves in presence of a serious difficulty. It is
impossible to mentally follow every one of the many individual
molecules which compose even a very limited mass of gas. The path
followed by this molecule may be every instant modified by the chance
of running against another, or by a shock which may make it rebound in
another direction.
Public-domain text, read in full here on John Shaqi.
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