M. Duhem has approached the problem from another side, and endeavours
to bring it within the range of thermodynamics. Yet ordinary
thermodynamics could not account for experimentally realizable states
of equilibrium in the phenomena of viscosity and friction, since this
science declares them to be impossible. M. Duhem, however, arrives at
the idea that the establishment of the equations of thermodynamics
presupposes, among other hypotheses, one which is entirely arbitrary,
namely: that when the state of the system is given, external actions
capable of maintaining it in that state are determined without
ambiguity, by equations termed conditions of equilibrium of the
system. If we reject this hypothesis, it will then be allowable to
introduce into thermodynamics laws previously excluded, and it will be
possible to construct, as M. Duhem has done, a much more comprehensive
theory.
The ideas of M. Duhem have been illustrated by remarkable experimental
work. M. Marchis, for example, guided by these ideas, has studied the
permanent modifications produced in glass by an oscillation of
temperature. These modifications, which may be called phenomena of the
hysteresis of dilatation, may be followed in very appreciable fashion
by means of a glass thermometer. The general results are quite in
accord with the previsions of M. Duhem. M. Lenoble in researches on
the traction of metallic wires, and M. Chevalier in experiments on the
permanent variations of the electrical resistance of wires of an alloy
of platinum and silver when submitted to periodical variations of
temperature, have likewise afforded verifications of the theory
propounded by M. Duhem.
In this theory, the representative system is considered dependent on
the temperature of one or several other variables, such as, for
example, a chemical variable. A similar idea has been developed in a
very fine set of memoirs on nickel steel, by M. Ch. Ed. Guillaume. The
eminent physicist, who, by his earlier researches, has greatly
contributed to the light thrown on the analogous question of the
displacement of the zero in thermometers, concludes, from fresh
researches, that the residual phenomena are due to chemical
variations, and that the return to the primary chemical state causes
the variation to disappear. He applies his ideas not only to the
phenomena presented by irreversible steels, but also to very different
facts; for example, to phosphorescence, certain particularities of
which may be interpreted in an analogous manner.
Nickel steels present the most curious properties, and I have already
pointed out the paramount importance of one of them, hardly capable of
perceptible dilatation, for its application to metrology and
chronometry.[13] Others, also discovered by M. Guillaume in the course
of studies conducted with rare success and remarkable ingenuity, may
render great services, because it is possible to regulate, so to
speak, at will their mechanical or magnetic properties.
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