A green extractive matter, which comes in all vegetal bodies developed
under sunlight, next deserves a place by itself, because it is one of
the few organic bodies of which no rational analysis has ever been
pretended. Though we can not state the constitution of this
chlorophyl, we know that, except by turning acid in the stomach, it
remains inert on the human system, as one might imagine would happen
if he swallowed a bunch of green grass. _Lignin_, with which it
is always associated, is mere woody fibre, and has no direct physical
action. In no instance has any stomach been found to _digest_ it
save an insect's--some naturalists thinking that certain beetles make
their horny wing-cases of that. I believe one man did think he had
discovered a solvent for it in the gastric juice of the beaver, but
that view is not widely entertained. So far as it exists in opium it
can only act as a foreign substance and a mechanical irritant to the
human bowels. Next come two inert, indigestible, and very similar
gummy bodies, _mucilagin and bassorine_. Sugar, a powerfully
active volatile principle, and a fixed oil (probably allied to
turpentine) are the only other invariable constituents of opium
belonging to the great organic group of the hydro-carbons.
I now come to a group by far the most important of all. Almost
without exception the vegetable poisons belong to what are called the
"nitrogenous alkaloids." Strychnia, brucia, ignatia, calabarin,
woovarin, atropin, digitalin, and many others, including all whose
effect is most tremendous upon the human system, are in this
group. Not without insight did the early discoverers call nitrogen
_azote_, "the foe to life." It so habitually exists in the things
our body finds most deadly that the tests for it are always the first
which occur to a chemist in the presence of any new organic poison.
The nitrogenous alkaloids owe the first part of their name to the fact
of containing this element; the second part to that of their usually
making neutral salts with acids, like an alkaline base. The general
reader may sometimes have asked himself why these alkaloids are
diversely written--as, e.g., sometimes "_morphia,_" and sometimes
"_morphine,_" The chemists who regard them as alkalies write them
in the one way, those who consider them neutrals, in the other. Of
these nitrogenous alkaloids, even the nuts of the tree, which
furnishes the most powerful, _swift_ poison of the world,
contains but three--the above-named strychnia, brucia, and
ignatia--principles shared in common with its pathological congener,
the St. Ignatius bean. Opium may be found to contain _twelve_ of
them; but as one of these (cotarnin) may be a product of distillation,
and the other (pseudo-morphia) seems only an occasional constituent, I
treat them as ten in number--rationally to be arranged under three
heads.
Public-domain text, read in full here on John Shaqi.
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