The Phase Rule and Its ApplicationsFindlay, Alexander
Science
The Phase Rule and Its Applications
Findlay, Alexander
Chemistry, Physical and theoretical; Phase rule and equilibrium; Solution (Chemistry)
General Summary.--The systems which have been discussed in the present
chapter contained water as one of their components, and an anhydrous salt
as the other. It will, however, be clear that the relationships which were
found in the case of these will be found also in other cases where it is a
question of the equilibria between two components, which crystallize out in
the pure state, and only one of which possesses a measurable vapour
pressure. A similar behaviour will, for example, be found in the case of
many pairs of organic substances; and in all cases the equilibria will be
represented by a diagram of the general appearance of Fig. 29 or Fig. 30.
That is to say: Starting from the fusion point of component I., the system
will pass, by progressive addition of component II., to regions of lower
temperature, until at last the cryohydric or eutectic point is reached. On
further addition of component II., the system will pass to regions of
higher temperature, the solid phase now being component II. If the fused
components are miscible with one another in all proportions a continuous
curve will be obtained leading up to the point of fusion of component II.
Slight changes of direction, it is true, due to changes in the crystalline
form, may be found along this curve, {132} but throughout its whole course
there will be but one liquid phase. If, on the other hand, the fused
components are not miscible in all proportions, then the second curve will
exhibit a marked discontinuity, and two liquid phases will make their
appearance.
* * * * *
{133}
CHAPTER VIII
SOLUTIONS OF SOLIDS IN LIQUIDS, ONLY ONE OF THE COMPONENTS BEING VOLATILE
B.--HYDRATED SALT AND WATER.
In the preceding chapter we discussed the behaviour of systems formed of
two components, only one of which was volatile, in those cases where the
two components separated from solution in the pure state. In the present
chapter we shall consider those systems in which combination between the
components can occur with the formation of definite compounds; such as are
found in the case of crystalline salt hydrates. Since a not inconsiderable
amount of study has been devoted to the systems formed by hydrated salts
and water, systems which are of great chemical interest and importance, the
behaviour of these will first call for discussion in some detail, and it
will be found later that the relationships which exist in such systems
appear also in a large number of other two-component systems.
The systems belonging to this group may be divided into two classes
according as the compounds formed possess a definite melting point, _i.e._
form a liquid phase of the same composition, or do not do so. We shall
consider the latter first.
1. _The Compounds formed do not have a Definite Melting Point._
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