The Phase Rule and Its ApplicationsFindlay, Alexander
Science
The Phase Rule and Its Applications
Findlay, Alexander
Chemistry, Physical and theoretical; Phase rule and equilibrium; Solution (Chemistry)
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| Liquid solution. | Solid solution.
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Temperature. | | | |
| Per cent. | Per cent. | Per cent. | Per cent.
| naphthalene. | acid. | naphthalene. | acid.
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62° | -- | 100 | -- | 100
60° | 4.0 | 96.0 | 1.7 | 98.3
55° | 21.0 | 79.0 | 2.1 | 97.9
53.5° | 29.4 | 70.0 | -- | --
55° | 31.3 | 68.7 | 59.6 | 40.4
60° | 42.4 | 57.6 | 80.3 | 19.7
65° | 53.3 | 46.7 | 89.2 | 10.8
70° | 69.7 | 2.3 | 95.4 | 4.6
75° | 84.4 | 15.6 | 96.6 | 3.4
79.9° | 100 | -- | 100 | --
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At the eutectic point the liquid solution is in equilibrium with two
different mixed crystals the composition of which is represented by D and E
respectively. If, therefore, a fused mixture containing the two components
A and B in the proportions represented by C is cooled down, it will, when
the temperature has reached the point C, solidify completely to a
_conglomerate_ of mixed crystals, D and E.
[Illustration: FIG. 57.]
[Illustration: FIG. 58.]
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