The Phase Rule and Its ApplicationsFindlay, Alexander
Science
The Phase Rule and Its Applications
Findlay, Alexander
Chemistry, Physical and theoretical; Phase rule and equilibrium; Solution (Chemistry)
We have assumed here that there is only one solid phase present, containing
A and B. To make sure that the solid phase is not a solid solution in which
A and B are present in the same ratio as in the liquid solution, a second
determination of the composition must be made, with different initial and
end concentrations. If the solid phase is a solid solution, the composition
will now be found different from that found previously.
The composition of the solid phase can, however, be determined in another
manner, viz. by studying the fusion curve and the curve of cooling. From
the form of the fusion curve alone, it is possible to decide whether the
two components {230} form a compound or not; and if the compounds which may
be formed have a definite melting point, the position of the latter gives
at once the composition of the compounds (cf. p. 231).
This method, however, cannot be applied when the compounds undergo
decomposition before the melting point is reached. In such cases, however,
the form of the cooling curve enables one to decide the composition of the
solid phase.[315] If a solution is allowed to cool slowly, and the
temperature noted at definite times, the graphic representation of the rate
of cooling will give a continuous curve; _e.g._ _ab_ in Fig. 76. So soon,
however, as a solid phase begins to be formed, the rate of cooling alters
abruptly, and the cooling curve then exhibits a break, or change in
direction (point _b_). When the eutectic point is reached, the temperature
remains constant, until all the liquid has solidified. This is represented
by the line _cd_. When complete solidification has occurred, the fall of
temperature again becomes uniform (_de_).
[Illustration: FIG. 76.]
[Illustration: FIG. 77.]
[Illustration: FIG. 78.]
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