The Phase Rule and Its ApplicationsFindlay, Alexander
Science
The Phase Rule and Its Applications
Findlay, Alexander
Chemistry, Physical and theoretical; Phase rule and equilibrium; Solution (Chemistry)
Since three components existing in three phases (two liquid and a vapour
phase) constitute a bivariant system, the final result, _i.e._ the
composition of the two layers and the total vapour pressure, will not
depend merely on the temperature, as in the case of two-component systems
(p. 102), but also on the composition of the mixture with which we start.
At constant temperature, however, all mixtures, the composition of which is
represented by a point on one and the same tie-line, will separate into the
same two liquid phases, although the relative _amounts_ of the two phases
will vary. If we omit the vapour phase, the condition of the system will
depend on the pressure as well as on the temperature and composition of the
initial mixture. By keeping the pressure constant, _e.g._ at atmospheric
pressure (by working with open vessels), the system again becomes
bivariant. We see, therefore, that the position of the curve _a_K_b_, or,
in other words, the composition of the different conjugate ternary
solutions, will vary with the temperature, and only with the temperature,
if we assume either constancy of pressure or the presence of the vapour
phase. Since at the critical point the condition is imposed that the two
liquid phases become identical, one degree of freedom is thereby {244}
lost, and therefore only one degree of freedom remains. The critical point,
therefore, depends on the temperature, and only on the temperature; always
on the assumption, of course, that the pressure is constant, or that a
vapour phase is present. Fig. 84, therefore, represents an isothermal
(p. 239).
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account