The Phase Rule and Its ApplicationsFindlay, Alexander
Science
The Phase Rule and Its Applications
Findlay, Alexander
Chemistry, Physical and theoretical; Phase rule and equilibrium; Solution (Chemistry)
the critical temperature K is 92°, and the composition at this ternary
critical point is--
Water 59 per cent.
Acetone 12 "
Phenol 29 "
[Illustration: FIG. 88.]
The difference between the two classes of systems just mentioned, is seen
very clearly by a glance at the Figs. 88 and 89, which show the projection
of the isothermals on the base of the prism. In Fig. 88, the projections
yield paraboloid curves, the two branches of which are cut by one side of
the triangle; and the critical point is represented by a point on {249}
this side. In the second case (Fig. 89), however, the projections of the
isothermals form ellipsoidal curves surrounding the supreme critical point,
which now lies _inside the triangle_. At lower temperatures, these
isothermal boundary curves are cut by a side of the triangle; at the
critical temperature, _k"_, of the binary system AB, the boundary curve
_touches_ the side AB, while at still higher temperatures the boundary
curve comes to lie entirely within the triangle. At any given temperature,
therefore, between the critical point of the binary system (_k"_), and the
supreme critical point of the ternary system (K), each pair of the three
components are miscible with one another in all proportions; for the region
of heterogeneous systems is now bounded by a closed curve lying entirely
within the triangle. Outside this curve only homogeneous systems are found.
Binary mixtures, therefore, represented by any point on one of the sides of
the triangle must be homogeneous, for they all lie outside the boundary
curve for heterogeneous states.
[Illustration: FIG. 89.]
2. _The three components can form two pairs of partially miscible liquids._
In the case of the three components water, alcohol, and succinic nitrile,
water and alcohol are miscible in all proportions, but not so water and
succinic nitrile, or alcohol and succinic nitrile.
[Illustration: FIG. 90.]
[Illustration: FIG. 91.]
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