The Phase Rule and Its ApplicationsFindlay, Alexander
Science
The Phase Rule and Its Applications
Findlay, Alexander
Chemistry, Physical and theoretical; Phase rule and equilibrium; Solution (Chemistry)
solution, only when the latter has a definite composition. Lastly, the
ternary eutectic point, K, represents an invariant system; three solid
phases can exist in equilibrium with a ternary solution, only when the
latter has one fixed composition and when the temperature has a definite
value. This eutectic point, therefore, {255} has a perfectly definite
position, depending only on the nature of the three components.
Instead of employing the prism, the change in the composition of the
ternary solutions can also be indicated by means of the _projections_ of
the curves _k__{1}K, _k__{2}K, and _k__{3}K on the base of the prism, the
particular temperature being written beside the different eutectic points
and curves. This is shown in Fig. 96.
[Illustration: FIG. 96.]
The numbers which are given in this diagram refer to the eutectic points
for the system bismuth--lead--tin, the data for which are as
follows:--[331]
--------------------------------------------------------------------
Melting point of | Percentage composition of | Temperature of binary
pure metal. | binary eutectic mixture. | eutectic point.
--------------------------------------------------------------------
| Bi Pb Sn |
Bismuth, 268° | 55 45 -- | Bi--Pb, 127°
Lead, 325° | 58 -- 42 | Bi--Sn, 133°
Tin, 232° | -- 37 63 | Pb--Sn, 182°
--------------------------------------------------------------------
--------------------------------------------------
Percentage composition of | Temperature of ternary
ternary eutectic mixture. | eutectic point.
--------------------------------------------------
Bi Pb Sn |
52 32 16 | 96°
--------------------------------------------------
Formation of Compounds.--In the case just discussed, the components
crystallized out from solution in the pure state. If, however, combination
can take place between two of the components, the relationships will be
somewhat different; the curves which are obtained in such a case being
represented in Fig. 97. From the figure, we see that the two components B
{256} and C form a compound, and the freezing point curve of the binary
system has therefore the form shown in Fig. 64 (p. 209). Further, there are
two _ternary_ eutectic points, K_{1} and K_{2}, the solid phases present
being A, B, and compound, and A, C, and compound respectively.
[Illustration: FIG. 97.]
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