The Phase Rule and Its ApplicationsFindlay, Alexander
Science
The Phase Rule and Its Applications
Findlay, Alexander
Chemistry, Physical and theoretical; Phase rule and equilibrium; Solution (Chemistry)
If we again employ rectangular co-ordinates for the graphic {291}
representation of the results, we have the two planes XOT and YOT (Fig.
115): the concentration of ferric chloride being measured along the X-axis,
the concentration of hydrogen chloride along the Y-axis, and the
temperature along the T-axis. The curve ABCDEFGHJK is, therefore, the
solubility curve of ferric chloride in water (p. 152), and the curve
A'B'C'D'E'F' the solubility curve of hydrogen chloride and its hydrates. B'
and D' are the melting points of the hydrates HCl,3H_{2}O and HCl,2H_{2}O.
In the space between these two planes are represented those systems in
which all three components are present. As already stated, only a few of
the possible ternary systems have been investigated, and these are
represented in Fig. 116. The figure shows the model resting on the
XOT-plane, so that the lower edge represents the solubility curve of ferric
chloride, the concentration increasing from right to left. The
concentration of hydrogen chloride is measured upwards, and the temperature
forwards. The further end of the model represents the isothermal surface
for -30°. The surface of the model on the left does not correspond with the
plane YOT in Fig. 115, but with a parallel plane which cuts the
concentration axis for ferric chloride at a point representing 65
gm.-molecules FeCl_{3} in 100 gm.-molecules of water. The upper surface
corresponds with a plane parallel to the axis XOT, at a distance
corresponding with the concentration of 50 gm.-molecules HCl in 100
gm.-molecules of water.
[Illustration: FIG. 115.]
Ternary Systems.--We pass over the binary system FeCl_{3}--H_{2}O, which
has already been discussed (p. 152), and the similar system HCl--H_{2}O
(see Fig. 115), and turn to the discussion of some of the ternary systems
represented by {292} points on the surface of the model between the planes
XOT and YOT. As in the case of carnallite, a plane represents the
conditions of concentration of solution and temperature under which a
ternary solution can be in equilibrium with a _single_ solid phase
(bivariant systems), a line represents the conditions for the coexistence
of a solution with two solid phases (univariant systems), and a point the
conditions for equilibrium with three solid phases (invariant systems).
[Illustration: FIG. 116.]
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