The Phase Rule and Its ApplicationsFindlay, Alexander
Science
The Phase Rule and Its Applications
Findlay, Alexander
Chemistry, Physical and theoretical; Phase rule and equilibrium; Solution (Chemistry)
In order, therefore, to decide what is the nature of a precipitate produced
by the hydrolysis of a normal salt, it is only necessary to ascertain
whether and how the composition of the precipitate alters with alteration
in the composition of the solution. If the composition of the solution is
represented by abscissæ, and the composition of the precipitate by
ordinates, the form of the curves obtained would enable us to answer our
question; for vertical lines would indicate the presence of two solid
phases (1st case), horizontal lines the presence of only one solid phase
(2nd case), and slanting lines the presence of mixed crystals (3rd case).
This method of representation cannot, however, be carried out in most
cases. It is, however, {298} generally possible to find one pair or several
pairs of components, the _relative amounts_ of which in the solution or in
the precipitate undergo change when, and only when, the composition of the
solution or of the precipitate changes. Thus, in the case of bismuth,
nitrate, and water, we can represent the ratio of Bi_{2}O_{3} : N_{2}O_{5}
in the precipitate as ordinates, and N_{2}O_{5} : H_{2}O in the solution as
abscissæ. A horizontal line then indicates a single solid phase, and a
vertical line two solid phases. An example of this is given in Fig.
118.[372]
[Illustration: FIG. 118.]
Bi_{2}O_{3}--N_{2}O_{5}--H_{2}O.--Although various systems have been
studied in which there is formation of basic salts,[373] we shall content
ourselves here with the description of some of the conditions for the
formation of basic salts of bismuth nitrate, and for their equilibrium in
contact with solutions.[374]
Three normal salts of bismuth oxide and nitric acid are known, viz.
Bi_{2}O_{3},3N_{2}O_{5},10H_{2}O(S_{10});
Bi_{2}O_{3},3N_{2}O_{5},4H_{2}O(S_{4}); and
Bi_{2}O_{3},3N_{2}O_{5},3H_{2}O(S_{3}). Besides these normal salts, there
are the following basic salts:--
{299}
Bi_{2}O_{3},N_{2}O_{5},2H_{2}O (represented by B_{1-1-2})
Bi_{2}O_{3},N_{2}O_{5},H_{2}O ( " " B_{1-1-1})
6Bi_{2}O_{3},5N_{2}O_{5},9H_{2}O ( " " B_{6-5-9})
2Bi_{2}O_{3},N_{2}O_{5},H_{2}O ( " " B_{2-1-1})
Probably some others also exist. The problem now is to find the conditions
under which these different normal and basic salts can be in equilibrium
with solutions of varying concentration of the three components. Having
determined the equilibrium conditions for the different salts, it is then
possible to construct a model similar to that for MgCl_{2}--KCl--H_{2}O or
for FeCl_{3}--HCl--H_{2}O, from which it will be possible to determine the
limits of stability of the different salts, and to predict what will occur
when we bring the salts in contact with solutions of nitric acid of
different concentrations and at different temperatures.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account