The Phase Rule and Its ApplicationsFindlay, Alexander
Science
The Phase Rule and Its Applications
Findlay, Alexander
Chemistry, Physical and theoretical; Phase rule and equilibrium; Solution (Chemistry)
The outline of this figure represents four ternary solutions in which the
component salts have a common acid or basic constituent; viz. sodium
chloride--sodium sulphate, sodium sulphate--potassium sulphate, potassium
sulphate--potassium chloride, potassium chloride--sodium chloride. These
four sets of curves are therefore similar to those discussed in the
previous chapter. In the case of sodium and potassium sulphate, a double
salt, _glaserite_ [K_{3}Na(SO_{4})_{2}] is formed. Whether glaserite is
really a definite compound or not is still a matter of doubt, since
isomorphic mixtures of Na_{2}SO_{4} and K_{2}SO_{4} have been obtained.
According to van't Hoff and Barscholl,[389] glaserite is an isomorphous
mixture; but Gossner[390] considers it to be a definite compound having the
formula K_{3}Na(SO_{4})_{2}. Points VIII. and IX. represent solutions
saturated with respect to glaserite and sodium sulphate, and glaserite and
potassium sulphate respectively.
The lines which pass inwards from these boundary curves represent solutions
containing three salts, but in contact with only two solid phases; and the
points where three lines meet, or where three fields meet, represent
solutions in equilibrium with three solid phases; with the phases, namely,
belonging to the three concurrent fields.
If it is desired to represent a solution containing the salts say in the
proportions, 51Na_{2}Cl_{2}, 9.5K_{2}Cl_{2}, 3.5K_{2}SO_{4}, the difficulty
is met with that two of the salts, sodium chloride and potassium sulphate,
lie on opposite axes. To overcome this difficulty the difference 51 - 3.5 =
47.5 is taken and measured off along the sodium chloride axis; and the
solution is therefore represented by the point 47.5Na_{2}Cl_{2},
9.5K_{2}Cl_{2}. In order, therefore, to find the amount of potassium
sulphate present {318} from such a diagram, it is necessary to know the
total number of salt molecules in the solution. When this is known, it is
only necessary to subtract from it the sum of the molecules of sodium and
potassium chloride, and the result is equal to twice the number of
potassium sulphate molecules. Thus, in the above example, the total number
of salt molecules is 64. The number of molecules of sodium and potassium
chloride is 57; 64 - 57 = 7, and therefore the number of potassium sulphate
molecules is 3.5.
Another method of representation employed is to indicate the amounts of
only two of the salts in a plane diagram, and to measure off the total
number of molecules along a vertical axis. In this way a solid model is
obtained.
The numerical data from which Fig. 124 was constructed are contained in the
following table, which gives the composition of the different solutions at
0°:--[391]
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account