The Phase Rule and Its ApplicationsFindlay, Alexander
Science
The Phase Rule and Its Applications
Findlay, Alexander
Chemistry, Physical and theoretical; Phase rule and equilibrium; Solution (Chemistry)
If, now, transformation occurred immediately the transition point was
reached, the sudden expansion and contraction would take place at the same
temperature. It is, however, generally found that there is a lag, and that
with rising temperature the relatively large expansion does not take place
until a temperature somewhat higher than the transition point; and with
falling temperature the contraction occurs at a temperature somewhat below
the transition point. This is represented in Fig. 130 by the lines BC and
EF. The amount of lag will vary from case to case, and will {332} also
depend on the length of time during which the dilatometer is maintained at
constant temperature.
As an example, there may be given the results obtained in the determination
of the transition point at which sodium sulphate and magnesium sulphate
form astracanite (p. 268).[399] The dilatometer was charged with a mixture
of the two sulphates.
--------------------------------------------------------
Temperature. | Level of oil in capillary. | Rise per 1°.
--------------------------------------------------------
15.6° | 134 |
16.6° | 141 | 7
17.6° | 148 | 7
18.6° | 154 | 6
19.6° | 161 | 7
20.6° | 168 | 7
21.6° | 241 | 73
22.6° | 243 | 2
23.6° | 251 | 8
24.6° | 259 | 8
--------------------------------------------------------
The transition point, therefore, lies about 21.6° (p. 268).
Public-domain text, read in full here on John Shaqi.
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