The Phase Rule and Its ApplicationsFindlay, Alexander
Science
The Phase Rule and Its Applications
Findlay, Alexander
Chemistry, Physical and theoretical; Phase rule and equilibrium; Solution (Chemistry)
[317] G. G. Stokes, _Proc. Roy. Soc._, 1891, 49. 174; Gibbs, _Trans. Conn.
Acad._, 1876, 3. 176; Roozeboom, _Zeitschr. physikal. Chem._, 1894, 15.
147.
[318] This figure has been taken from Ostwald's _Lehrbuch_, II. 2. 984.
[319] Roozeboom, _Zeitschr. physikal. Chem._, 1893, 12. 369.
[320] C. R. A. Wright, _Proc. Roy. Soc._, 1891, 49. 174; 1892, 50. 375.
[321] The distribution coefficient will not remain constant because, apart
from other reasons, the mutual solubility of chloroform and water is
altered by the addition of the acid.
[322] Bancroft, _Physical Review_, 1895, 3. 21; Schreinemakers, _Zeitschr.
physikal. Chem._, 1897, 23. 652, and subsequent volumes.
[323] C. R. A. Wright, _Proc. Roy. Soc._, 1889-1893.
[324] C. R. A. Wright, _Proc. Roy. Soc._, 1892, 50. 390.
[325] Bodländer, _Berg- und Hüttenmänn. Ztg._, 1897, 56. 331.
[326] C. R. A. Wright, _Proc. Roy. Soc._, _loc. cit._
[327] Schreinemakers, _Zeitschr. physikal. Chem._, 1900, 33. 78.
[328] Schreinemakers, _Zeitschr. physikal. Chem._, 1898, 27. 95.
[329] Schreinemakers, _Zeitschr. physikal. Chem._, 1899, 29. 577.
[330] Schreinemakers, _Zeitschr. physikal. Chem._, 1898, 25. 543.
[331] Charpy, _Compt. rend._, 1898, 126. 1569. Compare the curves for the
system KNO_{3}--NaNO_{3}--LiNO_{3} (H. R. Carveth, _Journ. Physical Chem._,
1898, 2. 209). Also alloys of Pb--Sn--Bi (E. S. Shepherd, _Journ. Physical
Chem._, 1902, 6. 527).
[332] It should be remembered that in the triangular diagram a _line_
parallel to one of the sides indicates, at a given temperature, a constant
amount of the component represented by the opposite corner of the triangle;
and, hence, points in a _plane_, parallel to one face of a right prism,
will indicate for different temperatures, variation in the amounts of two
components, but constancy in the amount of the third.
[333] _Gazzetta chim. ital._, 1898, 28. II. 520.
[334] Bruni, _Gazzetta chim. ital._, 1898, 28. II. 508; 1900, 30. I. 35.
[335] _Zeitschr. physikal. Chem._, 1900, 36. 168.
[336] For a discussion of these systems, see van't Hoff, _Bildung und
Spaltung von Doppelsalzen_ (Leipzig, 1897).
[337] Van Leeuwen, _Zeitschr. physikal. Chem._, 1897, 23. 35.
[338] Meyerhoffer, _Zeitschr. physikal. Chem._, 1889, 3. 336; 1890, 5. 97.
[339] Reicher, _Zeitschr. physikal. Chem._, 1887, 1. 220.
[340] For other examples of the formation and decomposition of double salts
at a transition point, the reader is referred to the work by van't Hoff,
already cited, on the _Bildung und Spaltung von Doppelsalzen_; or to
Bancroft, _Phase Rule_, p. 180.
[341] Bancroft, _Phase Rule_, p. 183.
[342] Roozeboom, _Zeitschr. physikal. Chem._, 1888, 2. 514.
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