The Phase Rule and Its ApplicationsFindlay, Alexander
Science
The Phase Rule and Its Applications
Findlay, Alexander
Chemistry, Physical and theoretical; Phase rule and equilibrium; Solution (Chemistry)
[362] Bancroft, _Phase Rule_, p. 203; Roozeboom, _Zeitschr. physikal.
Chem._, 1891, 8. 504, 531; Stortenbeker, _ibid._, 1895, 17. 643; 1897, 22.
60; 1900, 34. 108.
[363] Roozeboom, _Zeitschr. phys. Chem._, 1899, 28. 494; _Ber._, 1899, 32.
537.
[364] As, for instance, strychnine racemate, a compound of racemic acid
with the _optically active_ strychnine. This would be resolved into
strychnine _d_-tartrate and strychnine _l_-tartrate, which are not
enantiomorphous forms.
[365] Van't Hoff and Meyerhoffer, _Zeitschr. physikal Chem._, 1898, 27. 75;
1899, 30. 86. Fig. 113 is taken from the latter paper.
[366] Solid models constructed of plaster of Paris can be obtained from Max
Kaehler and Martini, Berlin.
[367] Instead of the present method of obtaining potassium chloride by
decomposing carnallite with water, advantage might be taken of the fact
that carnallite when heated to 168° undergoes decomposition with separation
of three-fourths of the potassium chloride (van't Hoff, _Acht Vorträge über
physikalische Chemie_, 1902, p. 32).
[368] Roozeboom and Schreinemakers, _Zeitschr. physikal. Chem._, 1894, 15.
588.
[369] These curves represent only portions of the isotherms, since the
systems in which a ternary solution is in equilibrium with solid hydrogen
chloride or a hydrate, have not been investigated.
[370] The numbers printed beside the points on the curves refer to the
number of the experiment in the original paper.
[371] Lash, Miller and Kenrick, _Journ. Physical. Chem._, 1903, 7. 259;
Allan, _Amer. Chem. Journ._, 1901, 25. 307.
[372] Allan, _Amer. Chem. Journ._, 1901, 25. 307.
[373] Hoitsema, _Zeitschr. physikal. Chem._, 1895, 17. 651; Allan, _loc.
cit._
[374] Rutten, _Zeitschr. anorgan. Chem._, 1902, 30. 342. Compare the system
BeO--SO_{3}--H_{2}O; Parsons, _Zeitschr. anorgan. Chem._, 1904, 42. 250.
[375] _Zeitschr. anorgan. Chem._, 1904, 40. 146.
[376] Schreinemakers, _Zeitschr. physikal. Chem._, 1893, 11. 76; Bancroft,
_Journ. Physical Chem._, 1902, 6. 179.
[377] _Zeitschr. anorgan. Chem._, 1904, 40. 148.
[378] _Zeitschr. physikal. Chem._, 1903, 43. 354.
[379] These equilibria were obtained by Boudouard, _Annales chim. phys._,
1901 [7], 24. 5. See also Hahn, _Zeitschr. physikal. Chem._, 1903, 42.
705; 44. 513.
[380] G. Preuner, _Zeitschr. physikal. Chem._, 1903, 47. 385.
[381] See Hahn, _Zeitschr. physikal. Chem._, 1903, 42. 705; 44. 513;
Boudouard, _Bull. Soc. chim._, [3], 25. 484; Bodländer, _Zeitschr. f.
Elektrochem._, 1902, 8. 833; R. Schenck and Zimmermann, _Ber._, 1903, 36.
1231, 3663; Schenck and Heller, _ibid._, 1905, 38. 2132; _Zeitschr. f.
Elektrochem._, 1903, 9. 691; Haber, _Thermodynamik technischer
Gasreaktionen_, p. 293 (Munich, 1903).
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