SO2 (sulphur dioxide) + H2O (water at low temperature)-->H2SO3
(sulphurous acid).
Another thing of very great importance is the cooling of the gases
to condense any water that may be present so that no hot gas will
reach the juice to be treated or combine with water in the pipes. The
equation represented when high temperatures are used is as follows:
SO2 (sulphur dioxide) + H2O (water) + O (high temperature)-->H2SO4
(sulphuric acid).
This last-named acid is very corrosive and a powerful investing
agent. It therefore has the property of rapidly destroying sucrose,
especially at a high temperature.
In the burning of sulphur it is well that as thorough a combination
as possible be obtained, else there will be a loss of sulphur,
which will deposit in the tubes and choke them, and more time will
be required for the process. The fumes from a well-regulated sulphur
furnace should contain from 15 to 16 per cent sulphurous acid. The
theoretical percentage obtainable is about 21 per cent of the acid.
Carbon dioxide.--In recent years carbon dioxide gas has found a very
useful application in the cane-sugar factories, where a good grade
of plantation sugar is desired.
Java factories have been the foremost in elaborating a system, through
their eminent technologists, so that today one may find the bulk of
the sugars they turn out from certain factories of a very satisfactory
grade and color. The method they use requires a great deal of skill
and attention in order to yield results that are satisfactory. It is
patterned after the process used in beet-sugar factories, with some
distinct modifications, which make it applicable to a juice containing
glucose, as is always the case with cane juices.
The object of applying any clarifying material is to effect a rise in
purity, and it is especially desirable to remove, in all cases, the
substance added, since this itself would tend to act as an impurity
and thus give a lower coefficient, if not properly removed. The
lime, which has been added previously, may be partly removed, as
the original precipitate formed, and any free lime or compound which
may be easily decomposed will combine with carbon dioxide, forming
calcium carbonate or limestone, which is quite insoluble and may be
very easily filtered off.
Ca(OH)2 (calcium hydroxide) + CO2-->CaCO3 (calcium carbonate) + H2O
(water).
Whether single or double carbonation is used, the same general methods
are employed, and results are expressed by the same chemical equation.
As stated before, the carbon dioxide may be recovered from the kilns
during the burning of lime, as is commonly done in the beet-sugar
industry, or it may be purchased in the form of liquid CO2 contained
in heavy iron containers. It is also feasible to use flue gases for
this purpose, where a good combustion is obtained, and after they
have been properly treated.
Public-domain text, read in full here on John Shaqi.
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