There is a bleaching preparation made in France known as "Redo,"
which is simply calcium hydrosulphite (CaS2O4). This is used in the
sugar industry to some extent, but it is claimed by many that the
results obtained are not as good as those obtained from the sodium
compound and that it deteriorates more easily.
Hydrosulphites, unlike sulphurous acid, will bleach equally as well in
alkaline or neutral medium, as in an acid medium. There is therefore
less danger from loss of sugar by inversion when they are used, while
the permanency of their effect is about the same. In any case where
juices have been bleached by sulphites, the result may be considered
as but temporary, since upon exposure to air and light the product
assumes a darker color. Hydrosulphites should therefore be introduced
as late in the process as possible. Where the material in the vacuum
pan is to be bleached, it is well to introduce this reagent just
before striking grain, thus furnishing a bright clear material which
will act as film over the nucleous of sucrose in the grain.
The chemical equation representing the change which takes place with
this reagent is as follows:
Na2S2O4 (sodium hydrosulphite) + O (oxygen) + H2O (water)-->2(Na H
S O3).
The amount to be used will depend absolutely upon individual
conditions, which may be ascertained only by experimentation. The
manufacturers of this product state that the amount of the material
used to that of dry sugar should be as 1 is to 10,000. In the writer's
experience, two or even three times this amount will usually be
required to give maximum results. As stated before, since there is
such a variance in the material to be treated, each operator will
be required to judge this to a great extent from the condition of
his product.
In these Islands where a very low grade of open-kettle sugar is still
made, which sells very cheaply, attempts are often made to bleach
it and recrystalize in order to make a centrifugal sugar.
While ordinary clarifying agents help to a great extent, if the melted
sugars are very dark from caramel and the decomposition products
of calcium glucosate, these reagents can not be expected to give a
light-colored juice. While they may improve conditions somewhat, the
only solution to such a problem is the use of the boneblack process.
Bluing.--In the production of plantation clarified sugars, and
sometimes of refinery crystals made from low-grade sugars, there is
a thin film surrounding each sugar crystal, which has a yellowish
tint. It is this that gives rise to the different grades of white
sugars, when color test only is considered. Since this yellowish
tinge will give way to a lighter color when neutralized with the
proper shade of blue, it is a very common practice to use some form
of bluing--usually that known as ultramarine--for this purpose.
Public-domain text, read in full here on John Shaqi.
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