The Preparation of Plantation RubberMorgan, Sidney
Science
The Preparation of Plantation Rubber
Morgan, Sidney
Rubber
Regarding the first of these claims, it has been shown[31] that the rubber
is not uniform in its behaviour on vulcanisation, and that its variability
is similar to that of rubber prepared by other processes.
[31] "Preparation and Vulcanisation of Plantation Rubber" (Eaton, Grantham,
and Day), Bulletin No. 27, F.M.S. Department of Agriculture, 1918.
The second claim has been the subject of much controversy. Experiments made
on estates under the supervision of, or in the absence of, the patentees
have given conflicting results. When varying factors have been eliminated,
the general conclusion was that no increase in weight of rubber was
obtained.
Private laboratory investigations led to a similar verdict, and Eaton[32]
records a confirmatory finding. More recently the claims made for the
process were investigated in Java[33] under varying conditions. Three
series of experiments were made:
[32] _Ibid._
[33] "Archief voor de Rubbercultuur" (De Vries and Spoon), Central Rubber
Station, Java, May, 1921.
(1) During the rainy monsoon and at a height of 1,800 feet.
(2) During the dry monsoon on a low-country estate.
(3) In the experimental gardens at Buitenzorg during bright sunny
weather and the most favourable conditions.
The agents used were (_a_) a mixture of alcohol and fusel oil, (_b_)
alcohol and petrol (benzene).
In these experiments no advantage in weight of rubber was obtained by the
Ilcken-Down process, and it would thus appear that the principal claim
fails to be substantiated.
The general composition of the rubber was approximately the same as
ordinary crepe obtained from undiluted latex. The rubber on vulcanisation
was found to be normal in behaviour, and was similar to the controls.
The coagulum ordinarily is affected by oxidation, and does not produce a
fine pale crepe. To remedy this defect the freshly prepared crepe is soaked
in a solution of sodium bisulphite and sulphuric acid.
It may be noted that in the recent experiments coagulation was effected in
vacuum in a specially designed wooden tank. From a study of the previous
section on "Spontaneous Coagulation," the reader will perceive that results
equal to those obtained by the Ilcken-Down process can be obtained
_without_ the necessity of using such agents as alcohol, petrol, or fusel
oil.
SLAB RUBBER.--This type of preparation has been the subject of much
discussion of recent years. There is nothing really special in the mode of
preparation, and in its original form "slab" rubber is only a thick sheet
which may be obtained by coagulation with acetic acid or other agents.
The coagulum, when removed from the serum, is subjected to comparatively
slight pressure, and the "slab" thus made is either placed to air-dry at
once, or may be subject to treatment in other liquids before drying.
The rubber is not allowed to remain until wholly dry, but is shipped while
still containing an appreciable percentage of enclosed moisture.
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