The Preparation of Plantation RubberMorgan, Sidney
Science
The Preparation of Plantation Rubber
Morgan, Sidney
Rubber
Raw rubber, as produced on the plantations, is almost invariably subjected
to the process of vulcanisation in the production of manufactured rubber
articles as we know them. Previous to the advent of plantation rubber, the
raw material was purchased by the manufacturer in a moist and impure
condition; frequently the rubber was adulterated with sand, dirt, and even
small stones. Consequently it was the invariable practice of the rubber
manufacturer to wash the raw rubber and convert it into crepe, which was
then hung and air-dried before use. The effect on the rubber, if of high
grade, was more severe than the washing and crepeing process on the
plantation, because the rubber was not a soft coagulum but generally dried
on the surface and semi-hard. The power required was considerable, and the
resulting crepe was consequently softer and more susceptible to heat than
plantation first latex crepe. Much of the "wild" rubber was soft and tacky
and inferior to "earth-scrap."
Vulcanising in its simplest aspect consists in mixing the rubber with
sulphur and heating the product under regulated conditions. The effect of
heat on the inferior grades of "wild" rubber is very marked. A soft,
sticky, and resinous material is transformed into a relatively tough and
elastic product. The effect of vulcanising on the better grades is less
marked, but immediately apparent. On the other hand, the effect of
vulcanising is least apparent on first latex plantation grades, because in
these we have a raw rubber prepared in a manner best suited to retain its
natural characteristics.
The need of vulcanising in the process of manufacturing rubber goods became
an axiom in pre-plantation days, and it is only quite recently that
attempts have been made to utilise raw rubber directly, without
vulcanisation, particularly for shoe soles. For this purpose a thick dense
crepe has been found satisfactory. Smoked sheet rubber is not generally
suitable, apparently owing to its microphysical structure. It is possible
that the process of rolling in the making of dense crepe compacts the
rubber particles, yielding a harder and more resilient product. The rolling
must not be carried too far, or the "working" of the rubber will
approximate to a preliminary mastication, and the product will be weakened.
The utilisation of crepe rubber directly has not yet been sufficiently
tested to enable a definite conclusion to be reached as to its future
scope, but it is obvious that for use in a raw state some modification in
preparation may be advantageous. The present method--_e.g._, coagulation
with acetic acid--does not yield the hardest and toughest rubber.
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