The Preparation of Plantation RubberMorgan, Sidney
Science
The Preparation of Plantation Rubber
Morgan, Sidney
Rubber
[37] The terms "curing" and "vulcanising" are generally employed as if
synonymous. Twiss has suggested that the former be applied in regard to a
change in physical properties, and the latter to the chemical change
whereby sulphur is combined with the rubber. The term "curing" is also
applied to the process of preparation of raw rubber. This must be kept in
mind so as to avoid confusion.
The degree of vulcanising will vary with the type of article to be
produced, and where a long life is desired, the tendency will be to
"undervulcanise"; but if the best mechanical properties are desired, the
tendency will be towards "overvulcanising," or, more correctly, "fully"
vulcanising. These considerations are aptly illustrated by reference to
pneumatic tyres. The inner tube need not possess high tensile strength,
provided that it is easily distensible, for the reason that, during use, it
is protected by the casing of the tyre proper, which confines and supports
it against the air-pressure applied. Inner tubes are therefore cured to
give a long life without developing the maximal physical properties. On the
other hand, the casing and tread of the tyre are required to withstand
severe mechanical conditions--particularly the constant flexing of the
cover, and the abrasion of the road surface. Tyres are not stored for any
long period, and, when put into service, have a limited period of useful
life. Consequently it is needful to develop maximal mechanical properties,
and vulcanisation is therefore carried further than in the manufacture of
inner tubes.
The rate of cure is controlled by a number of factors in addition to the
period and temperature of vulcanisation, in particular by the proportion
and nature of the other ingredients, especially sulphur and accelerators,
and also by the rubber itself. The main complaint as regards plantation
rubber is that it varies excessively in this respect. This matter will not
be discussed here, but is only introduced in order to explain the
importance of a constant rate of vulcanising to the manufacturer.
Plantation rubber should, therefore, be prepared so as to be as uniform as
possible in this respect, and the earlier part of this book gives full
details of the precautions advised, and in many cases adopted on the
plantations. Unfortunately, it is impossible to secure uniformity of
methods among all producers, even when they are Europeans, to say nothing
of the native producers, who account for perhaps one-third of the output.
Hence the importance of branding the rubber whenever possible, so that the
manufacturer may identify the rubber he purchases. If found satisfactory,
he can then secure further supplies from the same estate.
CHAPTER XXII
_TESTING OF PLANTATION RUBBER_
This subject may be subdivided into (_a_) Tests on the raw rubber; (_b_)
tests on the vulcanised rubber.
Public-domain text, read in full here on John Shaqi.
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