The Preparation of Plantation RubberMorgan, Sidney
Science
The Preparation of Plantation Rubber
Morgan, Sidney
Rubber
Raw rubber has been used to some extent for proofing purposes, as for the
manufacture of material for hoods of motor-cars. In this case no attempt is
made to preserve the physical properties. The rubber is masticated, mixed,
taken up with solvent and spread on the cloth exactly as if it were to be
vulcanised.
VULCANISED RUBBER.--We have already explained that the properties of
vulcanised rubber are dependent, to some extent, on the specific nature of
the raw rubber, or what De Vries terms the "inner qualities." That is to
say, differences appear on vulcanising which are not apparent from the
tests made on the raw rubber. Indeed, no investigation or analysis of the
raw rubber can enable one to foresee exactly how the rubber will behave on
vulcanisation. This illustrates the deficiency in our knowledge of
vulcanisation. When dealing with soft, resinous, or decomposed rubbers, it
is safe to anticipate a weak vulcanised product; but when we come to deal
with a number of samples of "standard" crepe or sheet--_i.e._, sheet or
crepe passing a certain standard of appearance--it is found that
differences in vulcanising properties cannot be foreseen. This matter is,
however, not so great a drawback as might be imagined, for reasonably well
prepared consignments of standard crepe or sheet differ but little from
one another, and the difference is mainly in the ease with which they break
down, or the rate or speed with which they vulcanise, and not with the
properties of the vulcanised product. Many of the plantation scrap grades
are equal to or nearly equal to "standard"; but some of these, as also the
rubber produced by native holders, show appreciable variation, and are the
source of most of the complaints which emanate from manufacturers. We shall
consider in turn the different grades and the effect of the usual surface
defects, such as mould, spots, etc.
CREPE RUBBER.--Oil marks and tackiness are the most serious defects from
the manufacturing standpoint. In the first part of this book we have shown
that damage caused by the so-called oil marks is not due to the oil, but to
traces of copper from the bearings of the machines. There are several
metallic compounds which cause deterioration of rubber both raw and
vulcanised, but copper is the most deadly, and rubber showing signs of
deterioration is rightly rejected by the manufacturers.
The only other defect of crepe rubber which has any bearing on its use in
manufacture is mould. Crepe rubber very seldom shows the ordinary surface
moulds not uncommon in sheet-rubber. There are, however, microscopic
growths which cause the development of coloured spots referred to in detail
in the earlier part of this book. The rubber hydrocarbon itself does not
appear to be affected by the moulds, but some of the serum constituents are
altered, with the result that the rubber vulcanises more slowly than it
otherwise would do. For this reason, crepe rubber with coloured spots may
give rise to trouble in the factory.
Public-domain text, read in full here on John Shaqi.
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