The Preparation of Plantation RubberMorgan, Sidney
Science
The Preparation of Plantation Rubber
Morgan, Sidney
Rubber
VARIATION IN PHYSICAL PROPERTIES.--A very large number of tests on
vulcanised specimens of plantation rubber have been carried out. The
rubber was almost invariably mixed with 7 to 10 per cent. of sulphur, and
no other ingredient, and vulcanised to give the maximal breaking load.
Unfortunately, this determination is subject to a very appreciable
experimental error, so that a large number of determinations are necessary
to give a reliable figure. It is quite impracticable to make a large number
of determinations in routine testing, on account of the labour involved. It
is usual to make five, or possibly ten, determinations, although some
investigators have been content with two. It is generally conceded that any
exceptionally low figures should be ignored, as probably caused by some
flaw or irregularity in the test piece. On the other hand, a study of
actual determinations shows an occasional excessively high figure, and it
is questioned whether this also should be left out of account. Others
ignore all except the highest figure, and take this to represent the true
breaking strain. As a consequence, the figures published by different
workers show considerable variation. De Vries has analysed a large number
of the figures obtained in systematic examination of estate samples, and
has constructed curves to illustrate the results.[47] It is open to
question how far the variations shown are attributable to experimental
error. The figures show, however, that the variation in breaking strain is
relatively small, and not very different for crepe and sheet rubber. In our
opinion, undue importance should not be attached to very high or
exceptionally high figures for breaking strain, which are occasionally met
with. Provided the figure does not fall much below the average, the sample
may be regarded as satisfactory. It is very seldom that any sample of first
latex estate rubber does not show satisfactory figures.
[47] "Estate Rubber," p. 466.
THE RATE OF CURE OR RATE OF VULCANISATION is subject to more exact
measurement, whether this be based on the physical or the chemical
properties of the rubber. If the testing machine be provided, as is usual,
with an autographic attachment, the position of the curves traced on the
recording paper gives a measurement of the rate of cure. These load-stretch
curves, to which reference has already been made, take up a definite
position in accordance with the physical properties; it is only the length
of the curve, or the point where it terminates (which gives the breaking
strain and elongation at break), which is largely fortuitous.
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