The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Curves of solubility give the means of estimating the _amount of salt
separated_ by the cooling to a known extent of a solution saturated
at a given temperature. For instance, if 200 parts of a solution of
potassium chloride in water saturated at a temperature of 60° be taken,
and it be asked how much of the salt will be separated by cooling the
solution to 0°, if its solubility at 60° = 45·7 and at 0° = 29·2? The
answer is obtained in the following manner: At 60° a saturated solution
contains 45·7 parts of potassium chloride per 100 parts by weight of
water, consequently 145·7 parts by weight of the solution contain 45·7
parts, or, by proportion, 200 parts by weight of the solution contain
62·7 parts of the salt. The amount of salt remaining in solution at 0°
is calculated as follows; In 200 grams taken there will be 137·3 grams
of water; consequently, this amount of water is capable of holding only
40·1 grams of the salt, and therefore in lowering the temperature from
60° to 0° there should separate from the solution 62·7-40·1 = 22·6 grams
of the dissolved salt.
The difference in the solubility of salts, &c., with a rise or fall
of temperature is often taken advantage of, especially in technical
work, for the separation of salts, in intermixture from each other.
Thus a mixture of potassium and sodium chlorides (this mixture is met
with in nature at Stassfurt) is separated from a saturated solution by
subjecting it alternately to boiling (evaporation) and cooling. The
sodium chloride separates out in proportion to the amount of water
expelled from the solution by boiling, and is removed, whilst the
potassium chloride separates out on cooling, as the solubility of this
salt rapidly decreases with a lowering in temperature. Nitre, sugar, and
many other soluble substances are purified (refined) in a similar manner.
Public-domain text, read in full here on John Shaqi.
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