The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[29] If a volume of gas _v_ be measured under a pressure of _h_ mm. of
mercury (at 0°) and at a temperature _t_° Centigrade, then,
according to the combined laws of Boyle, Mariotte, and of
Gay-Lussac, its volume at 0° and 760 mm. will equal the product
of _v_ into 760 divided by the product of _h_ into 1 + _a__t_°,
where _a_ is the co-efficient of expansion of gases, which is
equal to 0·00367. The weight of the gas will be equal to its
volume at 0° and 760 mm. multiplied by its density referred to
air and by the weight of one volume of air at 0° and 760 mm.
The weight of one litre of air under these conditions being =
1·293 gram. If the density of the gas be given in relation to
hydrogen this must be divided by 14·4 to bring it in relation to
air. If the gas be measured when saturated with aqueous vapour,
then it must be reduced to the volume and weight of the gas when
dry, according to the rules given in Note 1. If the pressure
be determined by a column of mercury having a temperature _t_,
then by dividing the height of the column by 1 + 0·00018_t_ the
corresponding height at 0° is obtained. If the gas be enclosed in
a tube in which a liquid stands above the level of the mercury,
the height of the column of the liquid being = H and its density
= D, then the gas will be under a pressure which is equal to the
barometric pressure less HD/13·59, where 13·59 is the density of
mercury. By these methods the _quantity of a gas_ is determined,
and its observed volume reduced to normal conditions or to parts
by weight. The physical data concerning vapours and gases must be
continually kept in sight in dealing with and measuring gases.
The student must become perfectly familiar with the calculations
relating to gases.
[30] According to Bunsen, Winkler, Timofeeff, and others, 100 vols. of
water under a pressure of one atmosphere absorb the following
volumes of gas (measured at 0° and 760 mm.):--
1 2 3 4 5 6 7 8 9 10 11
0° 4·82 2·35 2·15 179·7 3·54 130·5 437·1 688·6 5·4 104960 7·38
20° 3·10 1·54 1·83 90·1 2·32 67·0 290·5 362·2 3·5 65400 4·71
1, oxygen; 2, nitrogen; 3, hydrogen; 4, carbonic anhydride;
5, carbonic oxide; 6, nitrous oxide; 7, hydrogen sulphide; 8,
sulphurous anhydride; 9, marsh gas; 10, ammonia; 11, nitric
oxide. The decrease of solubility with a rise of temperature
varies for different gases; it is greater, the greater the
molecular weight of the gas. It is shown by calculation that
this decrease varies (Winkler) as the cube root of the molecular
weight of the gas. This is seen from the following table:
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