The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
The feeble development of the chemical affinities acting in solutions of
solids becomes evident from those multifarious methods by which _their
solutions are decomposed_, whether they be saturated or not. On heating
(absorption of heat), on cooling, and by internal forces alone, aqueous
solutions in many cases separate into their components or their definite
compounds with water. The water contained in solutions is removed
from them as vapour, or, by freezing, in the form of ice,[46] but the
_tension of the vapour of water_[47] held in solution is less than
that of water in a free state, and the _temperature of the formation
of ice_ from solutions is lower than 0°. Further, both the diminution
of vapour tension and the lowering of the freezing point proceed, in
dilute solutions, almost in proportion to the amount of a substance
dissolved.[48] Thus, if per 100 grams of water there be in solution
1, 5, 10 grams of common salt (NaCl), then at 100° the vapour tension
of the solutions decreases by 4, 21, 43 mm. of the barometric column,
against 760 mm., or the vapour tension of water, whilst the freezing
points are -0·58°, -2·91°, and -6·10° respectively. The above figures[49]
are almost proportional to the amounts of salt in solution (1, 5, and
10 per 100 of water). Furthermore, it has been shown by experiment that
the ratio of the diminution of vapour tension to the vapour tension
of water at different temperatures in a given solution is an almost
constant quantity,[50] and that for every (dilute) solution the ratio
between the diminution of vapour tension and of the freezing point is
also a tolerably constant quantity.[51]
[46] If solutions are regarded as being in a state of dissociation
(_see_ footnote 19, p. 64) it would be expected that they would
contain free molecules of water, which form one of the products
of the decomposition of those definite compounds whose formation
is the cause of solution. In separating as ice or vapour, water
makes, with a solution, a heterogeneous system (made up of
substances in different physical states) similar, for instance,
to the formation of a precipitate or volatile substance in
reactions of double decomposition.
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