The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[54] Those salts which separate out with water of crystallisation and
give several crystallohydrates form supersaturated solutions with
the greatest facility, and the phenomenon is much more common
than was previously imagined. The first data were given in the
last century by Loewitz, in St. Petersburg. Numerous researches
have proved that supersaturated solutions do not differ from
ordinary solutions in any of their essential properties. The
variations in specific gravity, vapour tension, formation of ice,
&c., take place according to the ordinary laws.
[55] Inasmuch as air, as has been shown by direct experiment, contains,
although in very small quantities, minute crystals of salts,
and among them sodium sulphate, air can bring about the
crystallisation of a supersaturated solution of sodium sulphate
in an open vessel, but it has no effect on saturated solutions of
certain other salts; for example, lead acetate. According to the
observations of De Boisbaudran, Gernez, and others, isomorphous
salts (analogous in composition) are capable of inducing
crystallisation. Thus, a supersaturated solution of nickel
sulphate crystallises by contact with crystals of sulphates of
other metals analogous to it, such as those of magnesium, cobalt,
copper, and manganese. The crystallisation of a supersaturated
solution, set up by the contact of a minute crystal, starts from
it in rays with a definite velocity, and it is evident that the
crystals as they form propagate the crystallisation in definite
directions. This phenomenon recalls the evolution of organisms
from germs. An attraction of similar molecules ensues, and they
dispose themselves in definite similar forms.
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