The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[57] _Emulsions_, like milk, are composed of a solution of glutinous
or similar substances, or of oily liquids suspended in a
liquid in the form of drops, which are clearly visible under a
microscope, and form an example of a mechanical formation which
resembles solution. But the difference from solutions is here
evident. There are, however, solutions which approach very near
to emulsions in the facility with which the substance dissolved
separates from them. It has long been known, for example, that
a particular kind of Prussian blue, KFe_{2}(CN)_{6}, dissolves
in pure water, but, on the addition of the smallest quantity
of either of a number of salts, it coagulates and becomes
quite insoluble. If copper sulphide (CuS), cadmium sulphide
(CdS), arsenic sulphide (As_{2}S_{5}) (the experiments with
these substances proceed with great ease, and the solution
obtained is comparatively stable), and many other metallic
sulphides, be obtained by a method of double decomposition (by
precipitating salts of these metals by hydrogen sulphide),
and be then carefully washed (by allowing the precipitate to
settle, pouring off the liquid, and again adding sulphuretted
hydrogen water), then, as was shown by Schulze, Spring, Prost,
and others, the previously insoluble sulphides pass into
transparent (for mercury, lead, and silver, reddish brown; for
copper and iron, greenish brown; for cadmium and indium, yellow;
and for zinc, colourless) solutions, which may be preserved
(the weaker they are the longer they keep) and even boiled, but
which, nevertheless, in time coagulate--that is, separate in an
insoluble form, and then sometimes become crystalline and quite
incapable of re-dissolving. Graham and others observed the power
shown by colloids (_see_ note 18) of forming similar _hydrosols
or solutions of gelatinous colloids_, and, in describing alumina
and silica, we shall again have occasion to speak of such
solutions.
In the existing state of our knowledge concerning solution, such
solutions may be looked on as a transition between emulsion and
ordinary solutions, but no fundamental judgment can be formed
about them until a study has been made of their relations to
ordinary solutions (the solutions of even soluble colloids freeze
immediately on cooling below 0°, and, according to Guthrie, do
not form cryohydrates), and to supersaturated solutions, with
which they have certain points in common.
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